A mobile, low-field nuclear magnetic resonance (NMR) sensor for onboard, inline detection of catalytic fines in fuel oil in the shipping industry is presented as an alternative to onshore laboratory measurements. Catalytic fines (called cat fines) are aluminosilicate zeolite catalysts utilized in the oil cracking process at refineries. When present in fuel oil, cat fines cause abrasive wear of engine parts and may ultimately lead to engine breakdown with large economical consequences, thereby motivating methods for inline measurements. Here, we report on a robust, mobile, and low-cost (27)Al NMR sensor for continuous online measurement of the level of catalytic fines in fuel oil onboard ships. The sensor enables accurate measurements of aluminum (catalytic fines) in ppm concentrations in good agreement with commercial laboratory reference measurements.
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http://dx.doi.org/10.1021/ac5014496 | DOI Listing |
J Colloid Interface Sci
December 2023
School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China.
The process of smelting and purifying the catalyst precursor salt from minerals is extremely complex, which directly leads to high catalyst costs and serious secondary pollution. In order to achieve energy saving and emission reduction in the catalyst preparation process, in-situ synthesis of catalyst materials from natural minerals is a new research direction. In this study, we firstly explored the optimal X value of MnFeO for the NH selective catalytic reduction of NO (NH-SCR) reaction, i.
View Article and Find Full Text PDFWaste Manag
August 2023
Catalysis, Reactors and Control Research Group (CRC), Dept. of Chemical and Environmental Engineering. University of Oviedo, Julián Clavería s/n, Oviedo 33006, Spain. Electronic address:
The feasibility of using dolomite powders, by-product from the refractory industry, as a CO adsorbent and as a catalyst for the acetone liquid-phase self-condensation is demonstrated in this article. The performance of this material can be largely improved by combining physical pretreatments (hydrothermal ageing, sonication) and thermal activation at different temperatures (500-800 °C). The highest CO adsorption capacity was observed for the sample after sonication and activated at 500 °C (46 mg·g).
View Article and Find Full Text PDFEnviron Res
April 2023
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China.
Environmental governance by photothermal materials especially for the separation of organic pollutants and regeneration of freshwater afford growing attention owing to their special solar-to-heat properties. Here, we construct a special functional nanosphere composed of an internal silica core coated by a thin carbon layer encapsulated plasmonic bimetallic FeCoO spinel (SiO@CoFe/C) by a facile self-assembled approach and tuned calcination. Through combining the advantage of bimetallic Fe-Co and carbon layer, this obtained nanosphere affords improved multiple environmental governing functions including peroxymonosulfate (PMS) activation to degrade pollutants and photothermal interfacial solar water evaporation.
View Article and Find Full Text PDFChemSusChem
May 2022
Department of Chemical and Pharmaceutical Sciences, Institution University of Trieste, Address 1 Via L. Giorgieri 1, 34127, Trieste, Italy.
The lipase-catalyzed polycondensation of azelaic acid and glycerol is investigated according to a Design-of-Experiment approach that helps to elucidate the effect of experimental variables on monomer conversion, M and regioselectivity of acylation of glycerol. Chemometric analysis shows that after 24 h the reaction proceeds regardless of the presence of the enzyme. Accordingly, the biocatalyst was removed after a first step of synthesis and the chain elongation continued at 80 °C.
View Article and Find Full Text PDFAcc Chem Res
March 2019
Laboratory of RNA Biology , Institute of Biophysics, Chinese Academy of Sciences , 15 Datun Road , Chaoyang District, Beijing 100101 , China.
Many artificial enzymes that catalyze redox reactions have important energy, environmental, and medical applications. Native metalloenzymes use a set of redox-active amino acids and cofactors as redox centers, with a potential range between -700 and +800 mV versus standard hydrogen electrode (SHE, all reduction potentials are versus SHE). The redox potentials and the orientation of redox centers in native metalloproteins are optimal for their redox chemistry.
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