Light-emitting diodes (LEDs) are becoming increasingly important for general lighting applications. The remote phosphor technology, with the phosphor located at a distance from the LEDs, offers an increased extraction efficiency for phosphor converted LEDs compared to intimate phosphor LEDs where the phosphor is placed directly on the die. Additionally, the former offers new design possibilities that are not possible with the latter. In order to further improve the system efficiency of remote phosphor LEDs, realistic simulation models are required to optimize the actual performance. In this work, a complete characterization of a remote phosphor converter (RPC) consisting of a polycarbonate diffuser plate with a phosphor coating on one side via the bi-directional scattering distribution function (BSDF) is performed. Additionally, the bi-spectral BSDF which embraces the wavelength conversion resulting from the interaction of blue light with the RPC is determined. An iterative model to predict the remote phosphor module power and photon budget, including the recuperation of backward scattered light by a mixing chamber, is introduced. The input parameters for the model are the bi-spectral BSDF data for the RPC, the emission of the blue LEDs and the mixing chamber efficiency of the LED module. A good agreement between experimental and simulated results was found, demonstrating the potential of this model to analyze the system efficiency with errors smaller than 4%.
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http://dx.doi.org/10.1364/OE.22.0A1079 | DOI Listing |
Nanoscale
January 2025
Inorganic Photoactive Materials, Institute of Inorganic Chemistry, Heinrich Heine University Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany.
Luminescence thermometry has emerged as a promising approach for remote, non-invasive temperature sensing at the nanoscale. One of the simplest approaches in that regard is single-ion luminescence Boltzmann thermometry that exploits thermal coupling between two radiatively emitting levels. The working horse example for this type of luminescence thermometry is undoubtedly the green-emitting upconversion phosphor β-NaYF:Er,Yb exploiting the thermal coupling between the two excited H and S levels of Er for this purpose.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okolna 2, 50-422 Wroclaw, Poland.
Luminescent manometry has gained significant popularity in recent years due to its capability to provide in situ pressure measurements in a remote manner. Therefore, there is a growing need to identify phosphors with pressure-dependent spectroscopic properties that can be utilized to develop highly sensitive pressure sensors operating over a wide pressure range. Hence, we present a novel temperature-invariant luminescent manometer based on Cr ion emission in pyroxene CaSrMgSiO:Cr.
View Article and Find Full Text PDFACS Omega
August 2024
Department of Inorganic Chemistry, Institute of Chemistry, Universidade Estadual de Campinas (Unicamp), R. Monteiro Lobato, 270, Campinas, São Paulo 13083-970, Brazil.
Luminescence thermometry is the state-of-the-art technique for remote nanoscale temperature sensing, offering numerous promising cutting-edge applications. Advancing nanothermometry further requires rational design of phosphors and well-defined, comprehensive mathematical treatment of spectral information. However, important questions regarding improper signal processing in ratiometric luminescence thermometry are continuously overlooked in the literature.
View Article and Find Full Text PDFInorg Chem
August 2024
Hubei Key Laboratory of Plasma Chemistry and Advanced Materials & Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Wuhan Institute of Technology, 430205 Wuhan, China.
The olivine-based gallate CaYGaO (CYG) with unique cationic ordering, rich lattice sites, and self-photoluminescence (PL) is suitable for application as a host of phosphor. However, research in this area is still in its early stages, especially in high-quality full-spectrum white lighting. Herein, novel CYG: Bi/Eu with a controllable PL property is designed based on energy transfer and superposition of emissions from blue self-PL, blue PL of Bi, and red-PL of Eu.
View Article and Find Full Text PDFNanotechnology
April 2024
St. Petersburg State University, Universitetskaya nab. 7-9, 199034, St. Petersburg, Russia.
Remote thermal sensing has emerged as a temperature detection technique for tasks in which standard contact thermometers cannot be used due to environment or dimension limitations. One of such challenging tasks is the measurement of temperature in microelectronics. Here, optical thermometry using co-doped and mixed dual-center GdO:Tb/Eusamples were realized.
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