Engineering chiral Fe(salen)-based metal-organic frameworks for asymmetric sulfide oxidation.

Chem Commun (Camb)

School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China.

Published: August 2014

Two chiral porous Fe(salen)-based metal-organic frameworks are constructed and are shown to be efficient and recyclable heterogeneous catalysts for asymmetric oxidation of sulfides to sulfoxides with an enantioselectivity of up to 96%.

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Source
http://dx.doi.org/10.1039/c4cc03308fDOI Listing

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