Thin, ultra-flexible devices that can be manufactured in a process that covers a large area will be essential to realizing low-cost, wearable electronic applications including foldable displays and medical sensors. The printing technology will be instrumental in fabricating these novel electronic devices and circuits; however, attaining fully printed devices on ultra-flexible films in large areas has typically been a challenge. Here we report on fully printed organic thin-film transistor devices and circuits fabricated on 1-μm-thick parylene-C films with high field-effect mobility (1.0 cm(2) V(-1) s(-1)) and fast operating speeds (about 1 ms) at low operating voltages. The devices were extremely light (2 g m(-2)) and exhibited excellent mechanical stability. The devices remained operational even under 50% compressive strain without significant changes in their performance. These results represent significant progress in the fabrication of fully printed organic thin-film transistor devices and circuits for use in unobtrusive electronic applications such as wearable sensors.
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http://dx.doi.org/10.1038/ncomms5147 | DOI Listing |
Beilstein J Org Chem
December 2024
Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), CNRS-Université de Strasbourg (UMR 7504), F-67034 Strasbourg, France.
The high potential of non-covalent arene-fluoroarene intermolecular interactions in the design of liquid crystals lies in their ability to strongly promote self-assembly, improve the order and stability of the supramolecular mesophases, and enable tuneability of the optical and electronic properties, which can potentially be exploited for advanced applications in display technologies, photonic devices, sensors, and organic electronics. We recently successfully reported the straightforward synthesis of several mesogens containing four lateral aliphatic chains and derived from the classical triphenylene core self-assembling in columnar mesophases based on this paradigm. These mesogenic compounds were simply obtained in good yields by the nucleophilic substitution (SFAr) of various types of commercially available fluoroarenes with the electrophilic organolithium derivatives 2,2'-dilithio-4,4',5,5'-tetraalkoxy-1,1'-biphenyl (2Li- ).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Nankai University, School of Materials Science and Engineering, CHINA.
Chiral hybrid organic-inorganic metal halides (HOMHs) hold great promise in broad applications ranging from ferroelectrics, spintronics to nonlinear optics, owing to their broken inversion symmetry and tunable chiroptoelectronic properties. Typically, chiral HOMHs are constructed by chiral organic cations and metal anion polyhedra, with the latter regarded as optoelectronic active units. However, the primary design approaches are largely constrained to regulation of general components within structural formula.
View Article and Find Full Text PDFFood Chem
December 2024
Institute of Biochemical and Biomedical Engineering, Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei, 10608, Taiwan.
Development of a reliable tool to detect hydrogen peroxide (HO) and rutin in food-derived products and bioactive flavonoids is essential for food safety. Nevertheless, food/drug-based real samples are complex matrices that affect the sensor's specificity and sensitivity. For this purpose, we developed a simple electrochemical detection platform using covalent organic framework‑silver nanoparticles (COF-AgNPs).
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Chemical and Biological Engineering, University of Ottawa, 161 Louis Pasteur, Ottawa, Ontario K1N 6N5, Canada.
Developing sustainable electronics requires using materials that are either recyclable or biodegradable, without compromising on electrical performance. Here, we introduce a solution-processed biodegradable polymer blend consisting of a diketopyrrolopyrrole-based semiconducting polymer (DPP2T) and different mixtures of two biodegradable polymers, polycaprolactone (PCL) and polylactic acid (PLA). We find that controlling the ratio of components enables a reduction in semiconductor polymer loading (∼70:80% reduction) while maintaining or improving field-effect transistor performance.
View Article and Find Full Text PDFAnal Chem
December 2024
State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China.
Thin-film fluorescent chemosensors, characterized by their tunable design, high selectivity, and exceptional sensitivity, hold significant promise for gas detection applications. However, the simultaneous realization of the 3S attributes (sensitivity, selectivity, and stability) remains a formidable challenge, particularly in the underexplored field of near-infrared (NIR) gas detection. In this work, we employ an acceptor-donor-acceptor (A-D-A) molecular design strategy to drive the development of an organic semiconductor fluorescent material with a progressive red shift in the emission wavelength.
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