The development of chemical sensors has received widespread attention during the past two decades because of their extensive use in environmental monitoring and clinical analysis via rapid, accurate, reproducible, and low-cost methods. Chemically modified CPEs have frequently been employed as potentiometric sensors in trace analysis for metal ions, organic pollutants and biological substances. Most of these electrodes are operated via the ion-exchange process of the active component incorporated into the carbon paste matrix. This review article concentrates on such achievements in the context of the general development across the field. An overview of potentiometric sensors that are capable of detecting metal ions in environmental samples is presented and discussed. A survey on important advances in potentiometric sensors with regard to high selectivity, lower detection limit, and fast response time is presented in this review article.
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