A luminescent heptanuclear DyIr6 complex showing field-induced slow magnetization relaxation.

Chem Commun (Camb)

State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China.

Published: August 2014

The first example of iridium/lanthanide phosphonates, i.e. [DyIr6(ppy)12(bpp)2(bppH)4](CF3SO3)·8H2O (1) (ppy(-) = 2-phenylpyridine, bpp(2-) = 2-pyridylphosphonate) is reported. It shows dual functions with the photoluminescence and field-induced slow magnetization relaxation originating from the Ir and Dy moieties, respectively.

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Source
http://dx.doi.org/10.1039/c4cc02951hDOI Listing

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