In the title compound, C15H17N3OS, the dihedral angle between the mean planes of the 2-hy-droxy-napthyl ring system and the hydrazinecarbo-thio-amide group is 73.7 (3)°. In the crystal, weak O-H⋯S and C-H⋯O inter-actions and π-π stacking inter-actions involving one of the hy-droxy-napthyl rings with a centroid-centroid distance of 3.6648 (14) Å are observed, forming infinite chains along [010]. In addition, N-H⋯S inter-actions occur.
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http://dx.doi.org/10.1107/S1600536814012057 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
April 2024
Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse 1, D-53121 Bonn, Germany.
The title compound (CHNS, common name: -jasmone 4-ethyl-thio-semicarbazone) was synthesized by the equimolar reaction of -jasmone and 4-ethyl-thio-semicarbazide in ethanol facilitated by acid catalysis. There is one crystallographically independent mol-ecule in the asymmetric unit, which shows disorder of the terminal ethyl group of the jasmone carbon chain [site-occupancy ratio = 0.911 (5):0.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
February 2017
Universidade Federal de Sergipe (UFS), Departamento de Química, São Cristóvão, Brazil.
There are two crystallographically independent mol-ecules in the asymmetric unit of the title compound, CHNS, one of them being disordered over the methyl group [site-occupancy ratio = 0.705 (5):0.295 (5)].
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
March 2015
Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, India.
The title compounds, C13H13N3O2S·0.5H2O, (I), and C17H14ClN3OS, (II), are hydrazinecarbo-thio-amide derivatives. Compound (I) crystallizes with two independent mol-ecules (A and B) and a water mol-ecule of crystallization in the asymmetric unit.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
June 2014
Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA.
The title compound, C12H17N3OS, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the hydrazinecarbo-thio-amide group are 6.9 (4) and 37.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
June 2014
Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA.
In the title compound, C15H17N3OS, the dihedral angle between the mean planes of the 2-hy-droxy-napthyl ring system and the hydrazinecarbo-thio-amide group is 73.7 (3)°. In the crystal, weak O-H⋯S and C-H⋯O inter-actions and π-π stacking inter-actions involving one of the hy-droxy-napthyl rings with a centroid-centroid distance of 3.
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