In the title compound, C19H22N2O4, the six-membered cyclo-hexenone ring of the chromene unit adopts an envelope conformation, with the dimethyl-substituted C atom as the flap, while the pyran ring has a boat conformation. These two mean planes are inclined to one another by 6.65 (13)°·The benzene ring is normal to the 4H-chromene moiety mean plane, making a dihedral angle of 89.18 (5)°. The methyl-amine and nitro groups are slightly twisted from the chromene moiety mean plane, with torsion angles C-N-C-O = 1.70 (18) and O-N-C-C = 0.15 (18)°. The mol-ecular structure is characterized by an intra-molecular N-H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, mol-ecules are linked via pairs of weak C-H⋯O hydrogen bonds, forming inversion dimers. These dimers are connected by further C-H⋯O hydrogen bonds, forming sheets lying parallel to (10-1).

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051056PMC
http://dx.doi.org/10.1107/S1600536814010794DOI Listing

Publication Analysis

Top Keywords

moiety plane
8
c-h⋯o hydrogen
8
hydrogen bonds
8
bonds forming
8
77-dimethyl-2-methyl-amino-4-4-methyl-phenyl-3-nitro-78-di-hydro-4h-chromen-56h-one title
4
title compound
4
compound c19h22n2o4
4
c19h22n2o4 six-membered
4
six-membered cyclo-hexenone
4
ring
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!