In the tetra-hydro-furan solvate of the title salt, C12H36N6P3 (+)·C24H20B(-)·C4H8O, the cation features short P-P bond lengths [2.1111 (11) and 2.1364 (10) Å] and a distinctly bent P-P-P angle [104.67 (4)°] that confirm that the mol-ecule is not allene-like. In the crystal, the solvent mol-ecule is linked to the cation via a weak C-H⋯O hydrogen bond.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051105 | PMC |
| http://dx.doi.org/10.1107/S1600536814011258 | DOI Listing |
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Acta Crystallogr Sect E Struct Rep Online
June 2014
Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, N9B 3P4, Canada.
In the tetra-hydro-furan solvate of the title salt, C12H36N6P3 (+)·C24H20B(-)·C4H8O, the cation features short P-P bond lengths [2.1111 (11) and 2.1364 (10) Å] and a distinctly bent P-P-P angle [104.
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