The asymmetric unit of the title compound, C28H42N2O5·H2O, consists of one half of the organic mol-ecule and one half-mol-ecule of water, both of which are located on a mirror plane which passes through the central C atoms and the hydroxyl group of the heterocyclic system. The hydroxyl group at the central ring is disordered over two equally occupied positions. The six-membered ring adopts a chair conformation, and the 2-hy-droxy-benzyl substituents occupy the sterically preferred equatorial positions. The aromatic rings make dihedral angles of 75.57 (9)° with the mean plane of the heterocyclic ring. The dihedral angle between the two aromatic rings is 19.18 (10)°. The mol-ecular structure features two intra-molecular phenolic O-H⋯N hydrogen bonds with graph-set motif S(6). In the crystal, mol-ecules are connected via O-H⋯O hydrogen bonds into zigzag chains running along the a-axis direction.
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http://dx.doi.org/10.1107/S1600536814010769 | DOI Listing |
Inorg Chem
January 2025
State Key Laboratory of Molecular & Process Engineering, SINOPEC Research Institute of Petroleum Processing, Beijing 100083, China.
The ZSM-5 zeolite is the key active component in high-severity fluid catalytic cracking (FCC) catalysts and is routinely activated by phosphorus compounds in industrial production. To date, however, the detailed structure and function of the introduced phosphorus still remain ambiguous, which hampers the rational design of highly efficient catalysts. In this work, using advanced solid-state NMR techniques, we have quantitatively identified a total of seven types of P-containing complexes in P-modified ZSM-5 zeolite and clearly revealed their structure, location, and catalytic role.
View Article and Find Full Text PDFRSC Adv
January 2025
Gansu Zhongshang Food Quality Test and Detection Co., Ltd Lanzhou 730010 China.
Ferrihydrite (Fh), a widely distributed mineral in the environment, plays a crucial role in the geochemical cycling of elements. This study used experimental and computational approaches to investigate the adsorption behavior of seven heavy metal ions on Fh. The pH edge analysis revealed that the adsorption capacity followed the order: Pb > Cu > Zn > Cd > Ni > Co > Mn, with Pb showed the highest adsorption.
View Article and Find Full Text PDFCurr Med Chem
January 2025
School of Pharmacy, North Sichuan Medical College, Nanchong, 637000, China.
Objectives: Alzheimer's disease (AD) is the most prevalent neurodegenerative disorder, but no drugs can cure this disease. Chalcones possess good antioxidant activity, anti-neuroinflammatory activity, neuroprotective effects, inhibitory effects on Aβ aggregation, and Aβ disaggregation ability. Therefore, chalcones are ideal lead compounds, and the discovery of novel anti-AD agent-based chalcones is necessary.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
School of Light Industry & Chemical Engineering, Dalian Polytechnic University, Dalian 116034, PR China. Electronic address:
In this work, a new biomass boron adsorbent of N-methyl-D-glucosamine embedded sodium alginate/polyethyleneimine/polysiloxane composite aerogel (SKPN) was reported. Relevant characterization proved that the aerogel exhibited 3D porous structure with plenty of hydroxyl and amino functional groups, which was beneficial to the diffusion of boron and the chelation between boron and SKPN. Various parameters affecting the adsorption performance including pH value, contact time initial concentration, temperature and reusability were investigated.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemistry, Faculty of Science, Arak University, Arak 38481-77584, Iran; Institute of Nanosciences &Nanotechnology, Arak University, Arak, Iran. Electronic address:
The rapid industrialization and human activities in catchments have posed notable global challenges in removing of heavy metal contaminants from wastewater. Here, Schiff-bases (SB) of cyanoguanidine (CG) and salicylaldehyde (SA) were covalently grafted on a magnetic nanocomposite of chitosan to form a hybrid magnetic nanostructure (FeO@CS-CGSB). The synthesized structure was characterized using various techniques such as Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), dynamic light scattering (DLS), zeta potential, and Brunauer-Emmett-Teller surface area analysis (BET).
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