We present a systematic study of the effect of variation of the zinc oxide (ZnO) and copper indium gallium (di)selenide (CIGS) layer thickness on the absorption characteristics of CIGS solar cells using a simulation program based on finite element method (FEM). We show that the absorption in the CIGS layer does not decrease monotonically with its layer thickness due to interference effects. Ergo, high precision is required in the CIGS production process, especially when using ultra-thin absorber layers, to accurately realize the required thickness of the ZnO, cadmium sulfide (CdS) and CIGS layer. We show that patterning the ZnO window layer can strongly suppress these interference effects allowing a higher tolerance in the production process.
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http://dx.doi.org/10.1364/OE.22.00A425 | DOI Listing |
Small Methods
January 2025
Center for Photonics Information and Energy Materials, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, Guangdong, 518055, P. R. China.
Wide-bandgap perovskite solar cells (PVSCs), a promising top-cell candidate for high-performance tandem solar cells, often suffer from larger open-circuit voltage (V) deficits as the bandgap increases. Surface passivation is a common strategy to mitigate these V deficits. However, understanding the mechanisms underlying the differences in passivation effects among various types of molecules remains limited, which is crucial for developing universal interface passivation strategies and guiding the design of passivation molecules.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Nantes Université, CNRS, CEISAM, UMR 6230, F-44000, Nantes, France.
Chalcogenide-based thin-film solar cell optimized for rear illumination and used for CO reduction is presented. Central to this innovation is a thinner, Cu(In,Ga)S chalcopyrite absorber coated with a robust metallic top layer, which potentially surpasses the performance of conventional front-illuminated designs. Using cobalt quaterpyridine molecular catalyst, photocurrent densities for CO reduction exceeding 10 mA/cm at 0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Electronics and Electrical Engineering, Keio University, 4-1-1 Hiyoshi, Kohoku-ku, Yokohama, Kanagawa 223-8521, Japan.
Wide-bandgap chalcopyrite materials are attractive candidates for a wide variety of energy conversion devices such as the top cell of tandem-type photovoltaic devices and photoelectrochemical water splitting hydrogen evolution devices. Nevertheless, simultaneous realization of high open circuit voltage () and high fill factor (FF) values has been challenging, and thus, the photovoltaic performance has been limited. In this article, high and high FF values of wide-gap chalcopyrite CuGaSe thin-film solar cells are simultaneously demonstrated using an aluminum-induced back-surface field effect.
View Article and Find Full Text PDFHeliyon
September 2024
College of Physics and Electronic Science, Shanxi Datong University, Shanxi, 037009, China.
Wide-gap Cu(In,Ga)Se (CIGS) solar cells exhibit a superior match to the solar spectrum, resulting in a higher ideal efficiency ( ). However, in reality, their device is lower than that of narrow-gap CIGS solar cells. This study aims to identify the factors that limit the performance enhancement of wide-gap CIGS solar cells, focusing on the characteristics of the buffer layer.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2024
School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, P.R. China.
Polycrystalline Cu(InGaAl)Se (CIGAS) thin films were prepared on polyimide (PI) foils by depositing aluminum (Al) and CIGS precursor layers. Three ceramic CIGS quaternary targets with different sodium (Na) contents were used for investigating the influences of alkali doping at an annealing temperature of 500 °C. The Al concentration was enriched at the front interfaces of absorber films with different Na doping amounts after annealing.
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