We report on a direct-write system for patterning of arbitrary, high-quality, continuous liquid crystal (LC) alignment patterns. The system uses a focused UV laser and XY scanning stages to expose a photoalignment layer, which then aligns a subsequent LC layer. We intentionally arrange for multiple overlapping exposures of the photoalignment material by a scanned Gaussian beam, often with a plurality of polarizations and intensities, in order to promote continuous and precise LC alignment. This type of exposure protocol has not been well investigated, and sometimes results in unexpected LC responses. Ultimately, this enables us to create continuous alignment patterns with feature sizes smaller than the recording beam. We describe the system design along with a thorough mathematical system description, starting from the direct-write system inputs and ending with the estimated alignment of the LC. We fabricate a number of test patterns to validate our system model, then design and fabricate a number of interesting well-known elements, including a q-plate and polarization grating.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1364/OE.22.012691 | DOI Listing |
Mater Horiz
January 2025
School of Materials Science and Engineering, Peking University, Beijing 1008711, P. R. China.
Intelligent soft robots that integrate both structural color and controllable actuation ability have attracted substantial attention for constructing biomimetic systems, biomedical devices, and soft robotics. However, simultaneously endowing single-layer cholesteric liquid crystal elastomer (CLCE) soft actuators with reversible 3D deformability and vivid structural color changes is still challenging. Herein, a multi-responsive (force, heat and light) single-layer 3D deformable soft actuator with vivid structural color-changing ability is realized through the reduced graphene oxide (RGO) deposition-induced Janus structure of the CLCE using a precisely-controlled evaporation method.
View Article and Find Full Text PDFACS Sens
January 2025
School of Materials Science and Engineering, Tongji University, Shanghai 201804, P. R. China.
Visual, sensitive, and selective detection of carcinogenic substances is highly desired in portable health protection and practical medicine production. However, achieving this goal presents significant challenges with the traditional single-mode sensors reported so far, as they have limited sensing mechanisms and provide only a single output signal. Here, we report an effective optical and electrical dual-mode sensor for the visual, sensitive, and selective detection of -nitrosodiethylamine (NDEA), a typical volatile carcinogenic substance, leveraging the synergy of ionic liquid-doped liquid crystals (IL-LC).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Tsinghua University, Institute of Nuclear and New Energy Technology, Room A320, Nengke Building, Qinghua Yuan No.1, Beijing, CHINA.
Exploring host-guest interactions to regulate hydrogen-bonding assembly offers a promising approach for developing advanced porous crystal materials (PCMs). However, screening compatible guests with appropriate geometries and host-guest interactions that could inhibit the dense packing of building blocks remains a primary challenge. This study presents a novel guest-induced crystallization (GIC) strategy, guided by thermodynamic calculations, to develop porous hydrogen-bonded organic frameworks (HOFs) using structurally challenging tetrazole building units.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Hokkaido University: Hokkaido Daigaku, WPI-ICReDD, Kita 21 Nishi 10, Kita-ku, 001-0021, Sapporo, JAPAN.
Fluorine-containing compounds have shown unparalleled impacts in the realm of functional molecules, and the ability to prepare novel structures has been crucial in unlocking new properties for applications in pharmaceutical and materials science. Herein, we report a copper-catalyzed, photoinduced defluorinative C‒O coupling between trifluoromethylarenes and alcohols. This method allows for direct access to a wide selection of difluorobenzylether (ArCF2OR) molecules, including a compound displaying liquid crystal behavior.
View Article and Find Full Text PDFLangmuir
January 2025
Center for Environmental Process Engineering, Department of Chemical Engineering and Polymer Science, Shahjalal University of Science and Technology, Sylhet 3114, Bangladesh.
Precise prediction of adsorption in a multicomponent system is vital for successful design of dye-contaminated industrial wastewater treatment processes. The present work looks for the reason behind the failure of the competitive Langmuir model (CLM) to describe adsorption in such systems, while the Langmuir model (LM) successfully describes the process for a single dye solution. With that end, derivations of LM and CLM have been revisited, and a criterion for the universality of active sites has been defined.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!