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AgSbF₆-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes. | LitMetric

AgSbF₆-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes.

Chem Commun (Camb)

Center for Catalytic Hydrocarbon Functionalizations, Institute of Basic Science (IBS) and Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 305-701, Korea.

Published: July 2014

AgSbF6-controlled diastereodivergent hydroarylation reactions were developed. Unprecedented and remarkable switching of the E/Z-stereoselectivity could be obtained by adjusting the AgSbF6 loading.

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Source
http://dx.doi.org/10.1039/c4cc03602fDOI Listing

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