The scope and limitations of oxygenases as catalysts for preparative organic synthesis is discussed.
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http://dx.doi.org/10.1039/c3cc49747j | DOI Listing |
Adv Mater
November 2024
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, 305-8565, Japan.
Recent advances in neural network-based computing have enabled human-like information processing in areas such as image classification and voice recognition. However, many neural networks run on conventional computers that operate at GHz clock frequency and consume considerable power compared to biological neural networks, such as human brains, which work with a much slower spiking rate. Although many electronic devices aiming to emulate the energy efficiency of biological neural networks have been explored, achieving long timescales while maintaining scalability remains an important challenge.
View Article and Find Full Text PDFExp Mol Med
October 2024
School of Life Sciences, University of Essex, Wivenhoe Park, Colchester, Essex, UK.
The clinical utility of hemoglobin-based oxygen carriers (HBOC) is limited by adverse heme oxidative chemistry. A variety of tyrosine residues were inserted on the surface of the γ subunit of recombinant fetal hemoglobin to create novel electron transport pathways. This enhanced the ability of the physiological antioxidant ascorbate to reduce ferryl heme and decrease lipid peroxidation.
View Article and Find Full Text PDFAcc Chem Res
October 2024
School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
ConspectusReticular chemistry has provided intriguing opportunities for systematically designing porous materials with different pores by adjusting the building blocks. Among them, framework materials have demonstrated outstanding performance for the design of new functional materials used in a broad range of fields, including energetic materials. Energetic materials are widely used for rockets, satellites, mining, and tunneling.
View Article and Find Full Text PDFChemphyschem
September 2024
Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune, 411008, India.
Various aza-crowns with different sizes and substituents have been explored computationally as potential hosts for stabilizing the explosive guest xenon trioxide (XeO) through σ-hole-mediated aerogen bonding interactions. Interestingly, aza-crowns demonstrate superior binding towards XeO compared to their oxygen and thio counterparts. However, unlike the latter cases, where the binding was found to be increasingly favorable with the increase in the size of the crowns, aza-crowns exhibit a variable size preference for XeO, peaking with aza-15-crown-5, and reducing thereafter with increase in crown size.
View Article and Find Full Text PDFNat Commun
February 2024
Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, School of Materials Science and Engineering, Peking University, 100871, Beijing, China.
Developing a CO-utilization and energy-storage integrated system possesses great advantages for carbon- and energy-intensive industries. Efforts have been made to developing the Zn-CO batteries, but access to long cycling life and low charging voltage remains a grand challenge. Here we unambiguously show such inefficiencies originate from the high-barrier oxygen evolution reaction on charge, and by recharging the battery via oxidation of reducing molecules, Faradaic efficiency-enhanced CO reduction and low-overpotential battery regeneration can be simultaneously achieved.
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