Polar organic chemical integrative samplers (POCIS) were deployed in the vicinity of an offshore oil installation and analyzed for naphthenic acids (NAs). The POCIS accumulated a range of mono- to tetracyclic NAs, with different degrees of alkylation, with monocyclic acids being the most abundant. Currently, POCIS or similar polar samplers may be the only way to measure exposure to NAs from offshore discharges in situ. In addition, they may be a valuable tool for monitoring similar organic acids in general.
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http://dx.doi.org/10.1002/etc.2651 | DOI Listing |
Sci Total Environ
January 2025
Department of Civil, Geological and Environmental Engineering, University of Saskatchewan, 57 Campus Dr, Saskatoon, Saskatchewan S7N 5A9, Canada; University of Lethbridge, Office of the Vice President (Research), Lethbridge, Alberta, Canada. Electronic address:
Sci Total Environ
January 2025
Department of Civil, Geological and Environmental Engineering, University of Saskatchewan, 57 Campus Dr, Saskatoon, Saskatchewan S7N 5A9, Canada; University of Lethbridge, Office of the Vice President (Research), Lethbridge, Alberta, Canada. Electronic address:
Naphthenic acids and naphthenic acid fraction compounds (NAFCs) are associated with production of unconventional petroleum resources, especially the Athabasca Oil Sands of Alberta, Canada. This complex mixture of acidic organic compounds is toxic to a variety of taxa, and so represents an important environmental management challenge. Thus, there is clear motivation to better understand the occurrence and characteristics of NAFCs in aquatic environments, their chemical behaviour, and environmental fate.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Department Chemical and Food Engineering, UFSC, Florianópolis, 88040-900, SC, Brazil.
Produced water management is a significant challenge for the oil and gas industry. Due to the large volumes and complex composition of this water, treatment requires special attention, resulting in high costs for companies in the sector. Naphthenic acids, known for their recalcitrance, add a layer of complexity to the treatment process.
View Article and Find Full Text PDFJ Am Soc Mass Spectrom
January 2025
LysisLogic Scientific Inc., Energy Transition Centre, Calgary, Alberta T2P 0H3, Canada.
This Perspective explores the transformative impact of ultrahigh-resolution mass spectrometry (UHR-MS), particularly Fourier transform ion cyclotron resonance (FT-ICR-MS), in the characterization of complex environmental and petroleum samples. UHR-MS has significantly advanced our ability to identify molecular formulas in complex mixtures, revolutionizing the study of biogeochemical processes and organic matter evolution on wide time scales. We start by briefly reviewing the main technological advances of UHR-MS in the context of petroleum and environmental applications, highlighting some of the challenges of the technology such as quantitation and structural identification.
View Article and Find Full Text PDFSci Total Environ
December 2024
Environment and Climate Change Canada, Saskatoon, Saskatchewan S7N 3H5, Canada. Electronic address:
The Athabasca oil sands region of Alberta, Canada contains one of the world's largest unconventional petroleum deposits. There is concern about residual contaminants where tailings are integrated during reclamation and the related adverse effects this may have. Some of the primary toxic organic contaminants in oilsands tailings are naphthenic acid fraction compounds (NAFCs).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!