Azaphosphatrane organocatalysts in confined space: cage effect in CO(2) conversion.

Chemistry

Laboratoire de Chimie, École Normale Supérieure de Lyon, 46, Allée d'Italie, F-69364 Lyon (France).

Published: July 2014

The endohedral functionalization of a molecular cage by an azaphosphatrane unit has allowed for the creation of highly engineered catalytic cavities for efficient conversion of CO2 into cyclic carbonates. Strong structure/activity/stability correlations have been demonstrated by careful adjustment of the size, shape, and electronic properties of the hemicryptophane host.

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Source
http://dx.doi.org/10.1002/chem.201402058DOI Listing

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