The rotationally resolved magnetic dipole absorption spectrum of the oxygen A-band b(1)Σ(g)(+)(v=0) <- X(3)Σ(g)(-)(v=0) perturbed by collisions with helium was studied theoretically using the impact approximation. To calculate the relaxation matrix, scattering calculations were performed on a newly computed helium-oxygen (b(1)Σ(g)(+)) interaction potential as well as on a helium-oxygen (X(3)Σ(g)(-)) interaction potential from the literature. The calculated integrated line cross sections and broadening coefficients are in good agreement with experimental results from the literature. Additionally, cavity ring-down experiments were performed in the wings of the spectral lines for a quantitative study of line-mixing, i.e., the redistribution of rotational line intensities by helium-oxygen collisions. It is shown that inclusion of line-mixing in the theory is required to reproduce the experimentally determined absolute absorption strengths as a function of the density of the helium gas.
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http://dx.doi.org/10.1063/1.4878666 | DOI Listing |
Discov Nano
December 2024
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, 611731, Sichuan, People's Republic of China.
LiTiO (LTO) batteries are known for safety and long lifespan due to zero-strain and stable lattice. However, their low specific capacity and lithium-ion diffusion limit practical use. This study explored modifying LTO through yttrium doping by hydrothermal method to form LiYTiO nanoparticles.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2025
Federal University of Rio Grande do Norte, Department of Materials Science and Engineering, 59078-970 Natal, RN, Brazil; Federal University of Rio Grande do Norte, Department of Theoretical and Experimental Physics, 59078-970 Natal, Brazil.
In this study, high-entropy spinel oxides (CoNiMnFeCr)O were synthesized using a PVP-assisted sol-gel method, marking the first report of this approach for producing high-entropy oxides. This method provides new insights into morphology customization through precise temperature control during calcination. Samples were calcined at 800, 900, and 1000 °C, and structural, optical, and electrochemical characterizations were performed to evaluate the impact of synthesis conditions on the oxygen evolution reaction (OER) performance.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
Beamline Research Division, Pohang Accelerator Laboratory, POSTECH, Pohang 37673, Republic of Korea.
Understanding and controlling the oxidation of layered materials remain critical issues in the final stages of their practical application in devices. Layered materials achieve a band gap by removing inversion symmetry. However, the oxidation process becomes complex, and the oxidation of these materials is not yet fully understood.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Medical Physics, School of Medicine, Shiraz University of Medical Sciences, Shiraz, Iran; Nanomedicine and Nanobiology Research Center, Shiraz University of Medical Sciences, Shiraz, Iran. Electronic address:
Implant-related infections are among the major post-surgery problems, and treatment of these infections is challenging due to the formation of biofilms by microorganisms such as Staphylococcus aureus. Herein, a novel gold-curcumin nanohybrid (GCNH) was synthesized for the first time and characterized. GCNH had a band gap energy of 2.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2025
Province-Ministry Co-construction Collaborative Innovation Center of Hebei Photovoltaic Technology, College of Physics Science and Technology, Hebei University, Baoding 071002, China. Electronic address:
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