We describe an efficient system for the direct partial oxidation of methane, ethane, and propane using iodate salts with catalytic amounts of chloride in protic solvents. In HTFA (TFA = trifluoroacetate), >20% methane conversion with >85% selectivity for MeTFA have been achieved. The addition of substoichiometric amounts of chloride is essential, and for methane the conversion increases from <1% in the absence of chloride to >20%. The reaction also proceeds in aqueous HTFA as well as acetic acid to afford methyl acetate. (13)C labeling experiments showed that less than 2% of methane is overoxidized to (13)CO2 at 15% conversion of (13)CH4. The system is selective for higher alkanes: 30% ethane conversion with 98% selectivity for EtTFA and 19% propane conversion that is selective for mixtures of the mono- and difunctionalized TFA esters. Studies of methane conversion using a series of iodine-based reagents [I2, ICl, ICl3, I(TFA)3, I2O4, I2O5, (IO2)2S2O7, (IO)2SO4] indicated that the chloride enhancement is not limited to iodate.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja502657g | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Insight into the evolution of phosphorous conversion, microbial community and functional gene expression during anaerobic co-digestion of food waste and excess sludge with spicy substances exposure.
Chemosphere
December 2024
Guangxi Key Laboratory of Environmental Processes and Remediation in Ecologically Fragile Regions, Guangxi Normal University, 15 Yucai Road, Guilin 541004, PR China; Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection (Guangxi Normal University), Ministry of Education, 15 Yucai Road, Guilin 541004, PR China. Electronic address:
Garlic and chili are widely used as food flavoring agents in food cooking, therefore might be accumulated in large amounts in food waste (FW). The effects of garlic and chili on the dissolution, hydrolysis, acidification and methanation in an anaerobic co-digestion system were investigated during the combined co-digestion of FW and excess sludge (ES). Additionally, the transformation of phosphorus form and microbial metabolism changes during the process were analyzed.
View Article and Find Full Text PDFElectrochemical optimization of bioelectrochemically improved anaerobic digestion for agricultural digestates' valorisation to biomethane.
J Environ Manage
December 2024
ENGIE Lab Crigen, 93240, Stains, Paris, France. Electronic address:
Bioelectrochemically improved anaerobic digestion (AD-BES) represents an upgrading strategy for existing biogas plants, consisting of the integration of bioelectrodes within the AD reactor. For this study, a series of laboratory-scale AD-BES reactors were operated, valorising agricultural digestates through the production of biogas. The reactors were inoculated and started-up with three different digestates, leading to significant differences in the microbial community developed on the bioelectrodes.
View Article and Find Full Text PDFThe role of biodegradable plastics in lignite anaerobic digestion: Changes of organics transformation and metabolic pathway.
Bioresour Technol
December 2024
School of Energy Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China. Electronic address:
Biodegradable plastics (BPs) and lignite, both rich in organic matter, present significant challenges for efficient conversion into clean energy. This study examined the anaerobic co-digestion of BPs and lignite under controlled laboratory conditions. The results demonstrated that the co-digestion of polylactic acid (PLA) and lignite (at a 1:2 mass ratio, with 5 g PLA and 10 g lignite as the model system) rapidly acclimated to the anaerobic environment, enhancing cumulative biogas production by 57 % compared to the mono-digestion of lignite alone.
View Article and Find Full Text PDFPhotocatalytic Oxidative Coupling of Methane to Ethane Using CO2 as a Soft Oxidant Over the Au/TiO2-Vo Nanosheets.
Angew Chem Int Ed Engl
December 2024
University of Science and Technology of China, Hefei National Research Center for Physical Sciences at Microscale, jinzhai road, hefei, CHINA.
Herein, we first report a photocatalytic OCM using CO2 as a soft oxidant for C2H6 production under mild conditions, where an efficient photocatalyst with unique interface sites is constructed to facilitate CO2 adsorption and activation, while concurrently boosting CH4 dissociation. As a prototype, the Au quantum dots anchored on oxygen-deficient TiO2 nanosheets are fabricated, where the Au-Vo-Ti interface sites for CO2 adsorption and activation are collectively disclosed by in situ Kelvin probe force microscopy, quasi in situ X-ray photoelectron spectroscopy and theoretical calculations. Compared with single metal site, the Au-Vo-Ti interface sites exhibit the lower CO2 adsorption energy and decrease the energy barrier of the *CO2 hydrogenation step from 1.
View Article and Find Full Text PDFCombined Reaction System for NH Decomposition and CO Methanation Using Hydrogen Permeable Membrane Reactor in 1D Model Analysis.
Membranes (Basel)
December 2024
Department of Chemistry and Biomolecular Science, Gifu University, Gifu 501-1113, Japan.
In a previous study, we developed an integrated reaction system combining NH decomposition and CO methanation within a membrane reactor, significantly enhancing reactor performance through efficient H separation. Ru/Ba/γ-AlO and Ru/ZrO were employed as catalysts for each reaction. To ensure the accuracy and reliability of our results, they were validated through 1D models using FlexPDE Professional Version 7.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!