Covalently crosslinked fly ash/poly(acrylic acid-co-acrylamide) composite microgels as novel magnetic selective adsorbent for Pb²⁺ ion.

J Colloid Interface Sci

State Key Laboratory of Applied Organic Chemistry and Institute of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China. Electronic address:

Published: July 2014

AI Article Synopsis

  • Researchers improved wastewater treatment by modifying magnetic fly ash particles with polymer groups to create a composite microgel for adsorbing lead ions.
  • They used an easy process called inverse suspension polymerization without extra organic crosslinkers.
  • The resulting magnetic microgels showed increased stability and allowed for easier separation from wastewater.

Article Abstract

In order to improve the performance of treating waste-water with wastes, the magnetic fly ash (FA) particles were surface-modified with polymerizable groups as the crosslinker for the copolymerization with acrylic acid (AA) and acrylamide (AM) by a facile inverse suspension polymerization process, without any foreign organic crosslinker added. The optimized beadlike magnetic fly ash/poly(acrylic acid-co-acrylamide) composite microgels (FA/P(AA-AM)) with 3-dimensional crosslinking skeleton structure were selected as the magnetic selective microgel adsorbent for Pb(2+) ion, through a series of L(9)(3(4)) orthogonal experiments. It was found that the magnetic FA particles could improve the strength stability of the FA/P(AA-AM) composite microgels, also provide the ability of magnetic separation.

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http://dx.doi.org/10.1016/j.jcis.2014.03.045DOI Listing

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