Poly[(μ4-decanedio-ato)cobalt(II)].

Acta Crystallogr Sect E Struct Rep Online

Dipartimento di Scienze Chimiche, Universita di Messina, Messina, Italy.

Published: May 2014

In the title compound, [Co(C10H16O4)] n , the Co(II) atom is bonded in a slightly distorted tetra-hedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of Co(II) atoms, one with the Co(II) atoms lying parallel to (100) [Co⋯Co = 4.653 (1) Å], the other lying parallel to (010) [Co⋯Co = 4.764 (1) Å].

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011297PMC
http://dx.doi.org/10.1107/S1600536814006011DOI Listing

Publication Analysis

Top Keywords

coii atoms
8
lying parallel
8
poly[μ4-decanedio-atocobaltii] title
4
title compound
4
compound [coc10h16o4]
4
[coc10h16o4] coii
4
coii atom
4
atom bonded
4
bonded distorted
4
distorted tetra-hedral
4

Similar Publications

Context: Cation-π and cation-lone pair interactions between 3d-metal (II) ions [Fe(II), Co(II), Ni(II) and Cu(II)] and furan are explored in the formation of 1:1 and 1:2 type complexes. Both cation-π (IE = -192.27 to -312.

View Article and Find Full Text PDF

Biosorption performance toward Co(II) and Cd(II) by irradiated Fusarium solani biomass.

Environ Geochem Health

January 2025

Soil and Water Research Department, Nuclear Research Center, Egyptian Atomic Energy Authority, Cairo, 13759, Egypt.

Fusarium solani biomass plays a significant role in water pollution remediation due to its ability to sequester heavy metals, particularly cobalt (Co(II)) and cadmium (Cd(II)), which pose severe environmental and health risks. This study aimed to identify fungi from sewage-contaminated sites and evaluate their efficiency in absorbing and reducing Co(II) and Cd(II) ions. The biosorption potential of irradiated Fusarium solani biomass for removing Co(II) and Cd(II) ions from aqueous solutions was investigated.

View Article and Find Full Text PDF

Reaction of Co(NCS) with 4-methyl-pyridine in water leads to the formation of single crystals of the title compound, [Co(NCS)(CHN)] . The asymmetric unit consists of two crystallographically independent thio-cyanate anions and two crystallographically independent 4-methyl-pyridine coligands in general positions, as well as of two different Co cations, of which one is located on a twofold rotational axis, whereas the second occupies a center of inversion. The methyl H atoms in both 4-methyl-pyridine ligands are disordered and were refined using a split model.

View Article and Find Full Text PDF

Tuning the Duplex Stability of DNA Oligonucleotides Containing Metal-Mediated Base Pairs of Imidazole-Derived Nucleobases.

Chemistry

December 2024

Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstr. 28/30, 48149, Münster, Germany.

Two artificial imidazole-derived nucleobases, Im (3H-imidazo[4,5-f]quinolin-5-ol) and Im (imidazole-4-carboxylate), were introduced into short DNA duplexes to systematically investigate their thermal stability upon metal ion coordination. Metal-mediated base pairs are formed with the 3d metal ions Co, Ni and Zn, as well as with the lanthanoid ions Eu and Sm, which induce a thermal stabilization of up to 8 °C upon binding. The latter are the first lanthanoid-mediated base pairs involving only four donor atoms that result in a significant duplex stabilization.

View Article and Find Full Text PDF

Crystal structure of -poly[[di-aqua-di-imida-zole-cobalt(II)]-μ-2,3,5,6-tetra-bromo-benzene-1,4-di-carboxyl-ato].

Acta Crystallogr E Crystallogr Commun

October 2024

Toyota Central R&D Labs., Inc., 41-1 Yokomichi, Nagakute, Aichi 480-1192, Japan.

The asymmetric unit of the title compound, [Co(CBrO)(CHN)(HO)] or [Co(Brbdc)(im)(HO)] , comprises half of Co ion, tetra-bromo-benzene-dicarboxylate (Brbdc), imidazole (im) and a water mol-ecule. The Co ion exhibits a six-coordinated octa-hedral geometry with two oxygen atoms of the Brbdc ligand, two oxygen atoms of the water mol-ecules, and two nitro-gen atoms of the im ligands. The carboxyl-ate group is nearly perpendicular to the benzene ring and shows monodentate coordination to the Co ion.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!