The mol-ecular structure of the title compound, C10H17BO3Si, features an intra-molecular O-H⋯O hydrogen bond; the boronic group group has an exo-endo conformation. In the crystal, the mol-ecules inter-act with each other by O-H⋯O hydrogen bonds, producing centrosymmetric dimers that are linked by weak π-π stacking inter-actions featuring specific short B⋯C contacts [e.g. 3.372 (2) Å], forming an infinite columnar structure aligned along the a-axis direction.
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http://dx.doi.org/10.1107/S1600536813031656 | DOI Listing |
An Acad Bras Cienc
January 2025
Universidade Federal de Sergipe, Departamento de Engenharia Química - DEQ, Laboratório de Laboratório de Biotecnologia Ambiental (LABAM), Campus São Cristóvão, Rodovia Marechal Rondon, s/n, Rosa Elze, 49100-000 São Cristóvão, SE, Brazil.
Lipases are enzymes that have an important role in the industry for their wide use, giving rise to a great interest in industrial bioprocesses due to their versatility. One of the applications is the enzymatic hydrolysis of waste oils. This work consists of evaluating the production of lipases using several concentrations of residual frying oil (RFO) and different pHs, through ANOVA analysis.
View Article and Find Full Text PDFSci Adv
January 2025
School of Chemistry and Chemical Engineering, Zhangjiang Institute for Advanced Study, Frontiers Science Center for Transformative Molecules, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
Metal single atoms are of increasing importance in catalytic reactions. However, the mass diffusion is yet substantially limited by the confined surface of the support in comparison to homogeneous catalysis. Here, we demonstrate that cylindrical micellar brushes with highly solvated poly(2-vinylpyridine) coronas can immobilize 33 types of metal single atoms with 8.
View Article and Find Full Text PDFEnviron Technol
January 2025
Department of Chemistry and Biology, Toronto Metropolitan University, Toronto, Canada.
Biosolids has several challenges, such as its high water content, huge volume, odour, and pathogen presence. Regulations require biosolids to be reused and disposed of safely. Polymer conditioning focuses on volume reduction, leaving pathogen and odour reduction unaddressed.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2025
Department of Chemical Sciences, Tata Institute of Fundamental Research, Mumbai 400005, India.
Heterogeneous catalysts have emerged as a potential key for closing the carbon cycle by converting carbon dioxide (CO) into value-added chemicals. In this work, we report a highly active and stable ceria (CeO)-based electronically tuned trimetallic catalyst for CO to CO conversion. A unique distribution of electron density between the defective ceria support and the trimetallic nanoparticles (of Ni, Cu, Zn) was established by creating the strong metal support interaction (SMSI) between them.
View Article and Find Full Text PDFPLoS One
January 2025
Department of Dravyaguna, Institute of Medical Sciences, Banaras Hindu University, Varanasi, India.
Cyclin-dependent kinases 4 and 6 (CDK4/6) are crucial regulators of cell cycle progression and represent important therapeutic targets in breast cancer. This study employs a comprehensive computational approach to identify novel CDK4/6 inhibitors from marine natural products. We utilized structure-based virtual screening of the CMNPD database and MNP library, followed by rigorous filtering based on drug-likeness criteria, PAINS filter, ADME properties, and toxicity profiles.
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