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Activation and deprotection of F-BODIPYs using boron trihalides. | LitMetric

Activation and deprotection of F-BODIPYs using boron trihalides.

Chem Commun (Camb)

Department of Chemistry, Dalhousie University, 6274 Coburg Road, PO Box 15000, Halifax, Nova Scotia B3H 4J3, Canada.

Published: July 2014

The activation of F-BODIPYs with boron trihalides, followed by treatment with a nucleophile, effects facile substitution at boron; using water as the nucleophile promotes deprotective removal of the -BF2 moiety and thereby production of the corresponding parent dipyrrin salt in quantitative yield under extremely mild conditions.

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Source
http://dx.doi.org/10.1039/c4cc02706jDOI Listing

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