The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses to CO2 and N2.
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| http://dx.doi.org/10.1039/c4dt00365a | DOI Listing |
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