We develop highly buoyant superhydrophobic films that mimic the three-dimensional structure of lotus leaves. The high buoyancy of these structure stems from mechanically robust bubbles that significantly reduce the density of the superhydrophobic films. These highly buoyant superhydrophobic films stay afloat on water surface while carrying a load that is more than 200 times their own weight. In addition to imparting high buoyancy, the incorporation of robust hydrophilic bubbles enables the formation of free-standing structures that mimic the water-collection properties of Namib Desert beetle. We believe the incorporation of robust bubbles is a general method that opens up numerous possibilities in imparting high buoyancy to different structures that needs to stay afloat on water surfaces and can potentially be used for the fabrication of lightweight materials. (Image on the upper left reproduced with permission from Yong, J.; Yang, Q.; Chen, F.; Zhang, D.; Du, G.; Si, J.; Yun, F.; Hou, X. A Bioinspired Planar Superhydrophobic Microboat. J. Micromech. Microeng. 2014, 24, 035006).
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http://dx.doi.org/10.1021/am5015343 | DOI Listing |
ACS Nano
January 2025
Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, P. R. China.
Along with the development of miniaturization, integration, and high power of electronic chips in the 5G and artificial intelligence era and their urgent need for technologies enabled to solve high heat flux dissipation in limited space, investigating bioinspired extreme superwettability surfaces with high-efficiency condensation heat transfer (CHT) performance has attracted great interest in academic and industrial communities. Compared with filmwise condensation of flat hydrophilic surfaces featured with continuous liquid films, dropwise condensation of flat hydrophobic surfaces is a more efficient type of energy transport way. However, discrete condensate drops can only shed off the hydrophobic flat surfaces under gravity until their sizes reach the capillary length of liquid, e.
View Article and Find Full Text PDFSmall Methods
January 2025
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan, 430062, P. R. China.
The insufficient density and discontinuity of solar energy of photothermal superhydrophobic flexible film seriously affect the practical application. Light energy harvesting and heat energy storage are effective ways to solve this problem. Inspired by the viscous temperature-regulating material within the inflorescence of Lobelia telekii and the arrangement of bracts on its surface, a flexible film for photoheat storage is proposed that integrated a three-order photoheat trap and one-order heat storage.
View Article and Find Full Text PDFLangmuir
January 2025
Materials Chemistry Centre, Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, U.K.
Durable and fluorine-free superhydrophobic films were fabricated by a simple two-step process involving the pretreatment of glass substrates with an epoxysilane, which acted as an adhesive. The next step involved the aerosol-assisted chemical vapor deposition of a simple mixture of polydimethylsiloxane (PDMS) and SiO nanoparticles (NPs). Various parameters were studied, such as deposition time as well as PDMS and SiO loadings.
View Article and Find Full Text PDFBiomimetics (Basel)
December 2024
Department of Chemistry, Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan 5290002, Israel.
Developing a durable multifunctional superhydrophobic coating on polymeric films that can be industrially scalable is a challenge in the field of surface engineering. This article presents a novel method for a scalable technology using a simple single-step fabrication of a superhydrophobic coating on polymeric films that exhibits excellent water-repelling and UV-blocking properties, along with impressive wear resistance and chemical robustness. A mixture of titanium precursors, tetraethylorthosilicate (TEOS), hydrophobic silanes and silica nano/micro-particles is polymerized directly on a corona-treated polymeric film which reacts with the surface via siloxane chemistry.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Key Laboratory of Multifunctional and Smart Systems, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China.
Personal thermal protection is crucial in extreme temperature environments, and the rising global temperatures present significant challenges in managing heat stress for individuals. Phase-change materials (PCMs) can absorb or release heat during phase transition to maintain a constant temperature, thus making them ideal innovative thermal protection materials. However, it is currently a bottleneck issue for using PCMs in wearable thermal protection systems due to a balance between the mechanical properties, latent heat, temperature resistance, and rapid response on demand.
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