Iridium-catalysed borylation of sterically hindered C(sp³)-H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide.

Chem Commun (Camb)

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.

Published: June 2014

The C(sp(3))-H bonds located on the methyl groups of an isopropyl group participate in iridium-catalysed C-H borylation with bis(pinacolato)diboron via a significant rate acceleration caused by a catalytic amount of t-BuOK.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c4cc01262cDOI Listing

Publication Analysis

Top Keywords

rate acceleration
8
catalytic amount
8
iridium-catalysed borylation
4
borylation sterically
4
sterically hindered
4
hindered csp³-h
4
csp³-h bonds
4
bonds remarkable
4
remarkable rate
4
acceleration catalytic
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!