When a carbenoid species generated from a tosylhydrazone is reacted with a cyclobutanol in the presence of a chiral rhodium catalyst, a C-C single bond of the cyclobutanol is cleaved, and the carbenoid carbon is inserted therein to furnish a ring-expanded cyclopentanol in an enantioselective manner.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja502229c | DOI Listing |
Publication Analysis
Top Keywords
carbenoid carbon
8
enantioselective insertion
4
insertion carbenoid
4
carbon c-c
4
c-c bond
4
bond expand
4
expand cyclobutanols
4
cyclobutanols cyclopentanols
4
cyclopentanols carbenoid
4
carbenoid species
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!