3-Anilino-5,5-di-methyl-cyclo-hex-2-enone.

Acta Crystallogr Sect E Struct Rep Online

Laboratoire des Produits Naturels d'Origine Végétale et de Synthèse Organique, PHYSYNOR Université Constantine 1, 25000 Constantine, Algeria.

Published: March 2014

In the title mol-ecule, C14H17NO, the 5,5-di-methyl-cyclo-hex-2-enone moiety is attached to an aniline group, the dihedral angle subtended [54.43 (3)°] indicating a significant twist. The hexaneone ring has a half-chair conformation with the C atom bearing two methyl groups lying 0.6384 (8) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0107 Å). The crystal packing can be described as alternating layers parallel to (-101), which are consolidated by N-H⋯O hydrogen bonds and C-H⋯π inter-actions.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998468PMC
http://dx.doi.org/10.1107/S160053681400186XDOI Listing

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