7-Nitro-2-phenyl-imidazo[2,1-b][1,3]benzo-thia-zole.

Acta Crystallogr Sect E Struct Rep Online

X-Ray Structural Centre, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St, B-334, Moscow 119991, Russian Federation.

Published: February 2014

In the title mol-ecule, C15H9N3O2S, the central imidazo[2,1-b][1,3]benzo-thia-zole heterotricyclic unit is essentially planar (r.m.s. deviation = 0.021 Å). The terminal phenyl ring and nitro group are twisted by 9.06 (1) and 11.02 (4)°, respectively, from the mean plane of the heterotricycle. In the crystal, mol-ecules are linked by π-π stacking inter-actions into columns along [100]; the inter-planar distance between neighboring imidazo[2,1-b][1,3]benzo-thia-zole planes within the columns is 3.370 (2) Å. Furthermore, the columns interact with each other by secondary S⋯O [2.9922 (10) and 3.1988 (11) Å] inter-actions, forming a three-dimensional framework.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998307PMC
http://dx.doi.org/10.1107/S1600536814000476DOI Listing

Publication Analysis

Top Keywords

7-nitro-2-phenyl-imidazo[21-b][13]benzo-thia-zole title
4
title mol-ecule
4
mol-ecule c15h9n3o2s
4
c15h9n3o2s central
4
central imidazo[21-b][13]benzo-thia-zole
4
imidazo[21-b][13]benzo-thia-zole heterotricyclic
4
heterotricyclic unit
4
unit essentially
4
essentially planar
4
planar rms
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!