Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre.

Chemistry

SPMS-CBC, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 (Singapore), Fax: (+65) 6791-1961.

Published: May 2014

Our recently synthesised phosphorus dication is observed to activate water (and methanol) under reactions conditions atypical for other systems containing a non-metal centre. This particular activation described as oxidative addition is quite rare and has been reserved exclusively for a couple of metal-based compounds.

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Source
http://dx.doi.org/10.1002/chem.201402356DOI Listing

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