Multiwall carbon nanotubes (MWCNTs) were easily and efficiently decorated with Pd nanoparticles through a vapor-phase impregnation-decomposition method starting from palladium acetylacetonates. The sensor device consisted on a film of sensitive material (MWCNTs-Pd) deposited by drop coating on platinum interdigitated electrodes on a SiO₂ substrate. The sensor exhibited a resistance change to ozone (O₃) with a response time of 60 s at different temperatures and the capability of detecting concentrations up to 20 ppb. The sensor shows the best response when exposed to O3 at 120 °C. The device shows a very reproducible sensor performance, with high repeatability, full recovery and efficient response.
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http://dx.doi.org/10.3390/s140406806 | DOI Listing |
Langmuir
January 2025
Department of Chemistry, Bharathiar University, Coimbatore 641 046, India.
Developing nonprecious metal-based electrocatalysts with exceptional activity and durability for water electrolysis remains a significant challenge. Herein, we report a highly efficient bifunctional electrocatalyst composed of sulfur-doped vanadium metal-organic frameworks (S@V-MOF) integrated with multiwalled carbon nanotubes (MWCNTs) to promote the synergistic effect between S@V-MOF and MWCNTs and modulate the electronic structure of the catalyst, which eventually enhanced its electrocatalytic performance. The S@V-MOF/MWCNT catalyst loaded at the Ni foam electrode exhibits remarkable activity for both the hydrogen evolution reaction (HER) in acidic media and oxygen evolution reaction (OER) in alkaline media, requiring overpotentials of 48 and 227 mV, respectively, to reach a current density of 10 mA cm.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
School of Environment, Northeast Normal University, Changchun 130117, China.
The disinfection of drinking water is essential for eliminating pathogens and preventing waterborne diseases. However, this process generates various disinfection byproducts (DBPs), which toxicological research indicates can have detrimental effects on living organisms. Moreover, the safety of these DBPs has not been sufficiently assessed, underscoring the need for a comprehensive evaluation of their toxic effects and associated health risks.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Department of Architecture and Civil Engineering, City University of Hong Kong, Tat Chee Avenue, Hong Kong.
Helical carbon nanotubes (HCNTs) with different geometrical properties were constructed and incorporated into nanocomposites for the investigation of the anti-crack mechanism. The interfacial mechanical properties of the nanocomposites reinforced with straight carbon nanotubes and various types of HCNTs were investigated through the pullout of HCNTs in the crack propagation using molecular dynamics (MD). The results show that the pullout force of HCNTs is much higher than that of CNTs because the physical interlock between HCNTs and matrices is much stronger than the van der Waals (vdW) interactions between CNTs and matrices.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Faculty of Engineering, University of Kragujevac, SestreJanjić 6, 34000 Kragujevac, Serbia.
Magnesium-based materials, which are known for their light weight and exceptional strength-to-weight ratio, hold immense promise in the biomedical, automotive, aerospace, and military sectors. However, their inherent limitations, including low wear resistance and poor mechanical properties, have driven the development of magnesium-based metal matrix composites (Mg-MMCs). The pivotal role of powder metallurgy (PM) in fabricating Mg-MMCs was explored, enhancing their mechanical and corrosion resistance characteristics.
View Article and Find Full Text PDFBiosensors (Basel)
January 2025
Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman 76318-85356, Iran.
In the current work, the MWCNTs/ZnO nanocomposite was successfully synthesized using simple method. Then, FE-SEM, XRD, and EDX techniques were applied for morphological and structural characterization. Afterward, a sensitive voltammetric sensor based on modification of a screen-printed carbon electrode (SPCE) using MWCNTs/ZnO nanocomposite was developed for the determination of doxorubicin in the presence of dacarbazine.
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