AI Article Synopsis
- A new self-assembled film was created using a polyoxomolybdate and a hemicyanine, demonstrating uniformity and reproducibility.
- The film forms J-aggregates, indicated by UV-visible spectral analysis.
- Photoelectrochemical tests revealed that the film generates a stable cathodic photocurrent, achieving a density of 5.1 μA/cm² under specific light conditions.
Article Abstract
A new electrostatically self-assembled film has been successfully prepared on quartz and indium-tin-oxide (ITO) coated glass substrates by alternating adsorption of a wheel-shaped polyoxomolybdate {Mo154} and a hemicyanine of (E)-1,1'-methylenebis(4-(4-(dimethylamino)styryl)pyridinium) bromide (H1). The UV-visible spectra demonstrated that the film was uniform, reproducible, and the H1 in the film forms the J-aggregation. Photoelectrochemical investigations showed that the films can generate stable cathodic photocurrent, and the cathodic photocurrent density of three-layer film was 5.1 microA/cm2 while irradiated with 100 mW/cm2 polychromatic light of 730 nm > lambda > 325 nm at an applied potential of -0.3 V versus saturated calomel electrode.
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| http://dx.doi.org/10.1166/jnn.2014.7962 | DOI Listing |
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