A physical operation of hydrodynamic orientation of an azobenzene supramolecular assembly with light and sound.

Chem Commun (Camb)

Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan.

Published: May 2014

Photoisomerizations of a newly designed azobenzene derivative reversibly change its self-assembly in a solution to form twisted supramolecular nanofibers and amorphous aggregates, respectively. When irradiating the sample solution with audible sound, the former assembly exhibits a LD response due to its hydrodynamic orientation, but the latter one is LD silent, in the sound-induced fluid flows.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c4cc02078bDOI Listing

Publication Analysis

Top Keywords

hydrodynamic orientation
8
physical operation
4
operation hydrodynamic
4
orientation azobenzene
4
azobenzene supramolecular
4
supramolecular assembly
4
assembly light
4
light sound
4
sound photoisomerizations
4
photoisomerizations newly
4

Similar Publications

The corrosion of low-alloy steel in ethanolamine solution, simulating steam generator chemistry, is studied by in situ chronopotentiometry and electrochemical impedance spectroscopy combined with ex situ analysis of the obtained oxide films and model calculations. Hydrodynamic calculations of the proposed setup to study flow-assisted corrosion demonstrate that turbulent conditions are achieved. Quantum chemical calculations indicate the adsorption orientation of ethanolamine on the oxide surface.

View Article and Find Full Text PDF

Filter feeding in devil rays is highly sensitive to morphology.

Proc Biol Sci

January 2025

Whitney Laboratory for Marine Bioscience, Department of Biology, University of Florida, 9505 North Ocean Shore Boulevard, St Augustine, FL 3208, USA.

Mobulid rays (manta and devil rays) use a highly specialized filtering apparatus to separate plankton food particles from seawater. Recent studies have indicated that captive vortices form within the microscale pores of the filter, which enhance filtration efficiency through a novel mechanism referred to as ricochet separation. The high throughput and clog resistance of this filtration process have led to the development of several bioinspired engineered filtration systems.

View Article and Find Full Text PDF

A comprehensive approach enabling a quantitative interpretation of poly-l-arginine (PARG) adsorption kinetics at solid/electrolyte interfaces was developed. The first step involved all-atom molecular dynamics (MD) modeling of physicochemical characteristics yielding PARG molecule conformations, its contour length, and the cross-section area. It was also shown that PARG molecules, even in concentrated electrolyte solutions (100 mM NaCl), assume a largely elongated shape with an aspect ratio of 36.

View Article and Find Full Text PDF

Dry ice is one of the world's most in-demand commodities for cold-chain distribution of temperature-sensitive products. It offers an effective cooling solution without requiring mechanical refrigeration or specialized equipment. Dry ice is commonly produced as pellets and blocks.

View Article and Find Full Text PDF

Temperature Dependence of Intermolecular Dynamics and Liquid Properties of Deep Eutectic Solvent, Reline.

J Phys Chem B

January 2025

Chemical, Biological and Macromolecular Sciences, S. N. Bose National Centre for Basic Sciences, J. D. Block, Sec.III, Salt Lake, Kolkata, West Bengal 700 098, India.

We investigated the temperature dependence of the intermolecular dynamics, including intermolecular vibrations and collective orientational relaxation, of one of the most typical deep eutectic solvents, reline, using femtosecond Raman-induced Kerr effect spectroscopy (fs-RIKES), subpicosecond optical Kerr effect spectroscopy (ps-OKES), and molecular dynamics (MD) simulations. According to fs-RIKES results, the temperature-dependent intermolecular vibrational band peak at ∼90 cm exhibited a redshift with increasing temperature. The density-of-state (DOS) spectrum of reline by MD simulations reproduced this fs-RIKES spectral feature.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!