To assess the potential effects on metal mobilization due to leakages of CO2 during its injection and storage in marine systems, an experimental set-up was devised and operated, using the polychaete Hediste diversicolor as the model organism. The objective was to study the effects of such leakage in the expected scenarios of pH values between 8.0 and 6.0. Polychaetes were exposed for 10 days to seawater with sediment samples collected in two different coastal areas, one with relatively uncontaminated sediment as reference (RSP) and the other with known contaminated sediment (ML), under pre-determined pH conditions. Survival and metal accumulation (Al, Fe, Mn, Cu, Zn, As and Hg) in the whole body of H. diversicolor were employed as endpoints. Mortality was significant at the lowest pH level in the sediment with highest metal concentrations. In general, metal concentrations in tissues of individuals exposed to the contaminated sediment were influenced by pH. These results indicate that ocean acidification due to CO2 leakages would provoke increased metal mobilization, causing adverse side effects in sediment toxicity.
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http://dx.doi.org/10.1016/j.envint.2014.03.008 | DOI Listing |
J Environ Sci (China)
July 2025
Key Laboratory of Pollution Ecology and Environmental Engineering, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China. Electronic address:
In sulfidic anoxic environments, iron sulfides are widespread solid phases that play an important role in the arsenic (As) biogeochemical cycle. This work investigated the transformation process of FeS-As coprecipitates, the concurrent behavior, and the speciation of associated As under anoxic conditions. The results showed that FeS-As coprecipitates could convert to greigite and pyrite.
View Article and Find Full Text PDFMol Cell Endocrinol
January 2025
Programa de Pós-graduação em Medicina (Endocrinologia), Faculdade de Medicina, Universidade Federal do Rio de Janeiro, Rio de Janeiro-RJ, Brazil; Centro de Pesquisa em Medicina de Precisão, Instituto de Biofísica Carlos Chagas Filho, Universidade Federal do Rio de Janeiro, Rio de Janeiro-RJ, Brazil; Programa de Pós-graduação em Ciências Biológicas (Fisiologia), Instituto de Biofísica Carlos Chagas Filho, Universidade Federal do Rio de Janeiro, Rio de Janeiro-RJ, Brazil.
The large-scale industrial production characteristic of the last century led to an increase in man-made compounds and mobilization of natural compounds, many of which can accumulate in the environment and organisms due to their bioaccumulation and biomagnification properties. The endocrine system is especially vulnerable to these compounds that are known as endocrine disruptor chemicals (EDCs). Thyroid hormones (THs) are essential for normal development and growth, besides being the main regulators of basal metabolic rate.
View Article and Find Full Text PDFEcotoxicol Environ Saf
January 2025
Hubei Key Laboratory of Yangtze Catchment Environmental Aquatic Science, School of Environmental Studies, China University of Geosciences, Wuhan 430074, PR China. Electronic address:
Microorganisms that utilize organic matter to reduce Fe oxides/hydroxides constitute the primary geochemical processes controlling the formation of high-arsenic (As) groundwater. Biogenic secondary iron minerals play a significant role in As migration. However, the influence of quinone electron shuttles and competitive anionic phosphate on this process has not been thoroughly studied.
View Article and Find Full Text PDFS D Med
October 2024
Monument Health Rapid City Clinic, Rapid City, South Dakota.
Immobilization induced hypercalcemia is an uncommon and serious disorder that requires a thorough evaluation to exclude more common causes of an elevated calcium. Although the pathogenesis is not clearly illuminated, immobilization results in an uncoupling between osteogenic and osteoclastic factors that maintain bone homeostasis. When calcemic bone resorption overwhelms urinary calcium excretion, blood hypercalcemia ensues.
View Article and Find Full Text PDFSci Total Environ
January 2025
School of the Environment, University of Queensland, QLD, Australia.
The transition to net zero emissions requires the capture of carbon dioxide from industrial point sources, and direct air capture (DAC) from the atmosphere for geological storage. Dissolved CO has reactivity to rock core, and while the majority of previous studies have concentrated on reservoir rock or cap-rock reactivity, the underlying seal formation may also react with CO. Drill core from the underlying seal of a target CO storage site was reacted at in situ conditions with pure CO, and compared with an impure CO stream with SO, NO and O that could be expected from hard to abate industries.
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