The chiral gold(i) complex enables enantioselective cycloisomerization-amination of 2-(alkynyl)phenyl boronic acids and diazenes in high yields. A wide scope of substrates bearing various functional groups was tolerated to generate structurally different hydrazide derivatives as a new type of atropisomer.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c4cc01397b | DOI Listing |
Publication Analysis
Top Keywords
asymmetric synthesis
4
synthesis heteroaryl
4
heteroaryl atropisomers
4
atropisomers gold-catalyzed
4
gold-catalyzed cycloisomerization-amination
4
cycloisomerization-amination cascade
4
cascade reaction
4
reaction chiral
4
chiral goldi
4
goldi complex
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!