Two rare 2D Ga/In-based coordination polymers in which one metal center coexists with three distinct aromatic ligands were synthesized. Helical channels along the 21 screw axis are exhibited to form a hcb net. The compounds exhibit tunable fluorescence from blue, green, white to yellow light by varying the temperature and solvents.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c3cc48867e | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Paddlewheel-type and half-paddlewheel-type diruthenium(II,II) complexes with 1,8-naphthyridine-2-carboxylate.
Dalton Trans
January 2025
Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060, Nishikawatsu, Matsue, Shimane, 690-8504, Japan.
Paddlewheel-type diruthenium(II,II) complexes are paramagnetic with two unpaired electrons ( = 1) and can be utilized as versatile building blocks for higher-order structures, such as supramolecular complexes, coordination polymers, and metal-organic frameworks, although they are generally highly air-sensitive. In this study, we developed an air-stable paddlewheel-type diruthenium(II,II) complex with two electron-withdrawing 1,8-naphthyridine-2-carboxylate (npc) ligands, [Ru(μ-npc)(OCMe)] (1). The two acetate ligands in 1 can be replaced by other carboxylate ligands; the solvothermal reactions of 1 with benzoic acid (HOCPh) yields the heteroleptic [Ru(μ-npc)(OCPh)] (2), whereas its reaction with 1,8-naphthyridine-2-carboxylic acid (Hnpc) produces the homoleptic [Ru(μ-npc)(η-npc)] (3).
View Article and Find Full Text PDFKinetic Separation of Butane Isomers Using a Formate Metal-Organic Framework.
Chempluschem
January 2025
Sun Yat-Sen University, School of Chemistry, CHINA.
n-butane (n-C4H10) and isobutane (i-C4H10) are important raw materials in chemical industry. The separation of the two hydrocarbon isomers via distillation is challenging and energy-consuming. Herein we report the adsorption behavior of a microporous cobalt formate framework [Co3(HCOO)6] for potential kinetic separation of butane isomers.
View Article and Find Full Text PDFCancer-targeted pro-theranostic bi-metallic organo-coordination nanoparticles.
Theranostics
January 2025
Departments of Radiology, Washington University in St. Louis, MO 63110, USA.
Cancer remains a leading cause of mortality, with aggressive, treatment-resistant tumors posing significant challenges. Current combination therapies and imaging approaches often fail due to disparate pharmacokinetics and difficulties correlating drug delivery with therapeutic response. In this study, we developed radionuclide-activatable theranostic nanoparticles (NPs) comprising folate receptor-targeted bimetallic organo-nanoparticles (Gd-Ti-FA-TA NPs).
View Article and Find Full Text PDFRh(III)-Catalyzed [4 + 2] Annulation and Dehydrogenative Annulation of -Chloroimines with Maleimides.
J Org Chem
January 2025
Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China.
We herein report a Rh(III)-catalyzed C-H bond coupling of -chloroimines with maleimides, in which the [4 + 2] annulation and dehydrogenative annulation processes can be selectively achieved by simply adjusting the reaction conditions. This protocol is compatible with various functional groups, shows exquisite selectivity, and presents a concise synthetic procedure to respective products in moderate to good yields. With all these merits, this strategy may be applicable in the construction of related azaheterocyclic skeletons.
View Article and Find Full Text PDFNanocellulose composites based on embedded europium-containing coordination polymers for the detection of antibiotics.
Int J Biol Macromol
January 2025
State Key Laboratory of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin 300457, PR China; Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Tianjin 300457, PR China; China Light Industry Key Laboratory of Papermaking and Biorefinery, Tianjin University of Science and Technology, Tianjin 300457, PR China. Electronic address:
Developing sensitive and reliable methods for detecting antibiotics in water solutions is essential for protecting public health and the environment. Here, we report a novel fluorescent film with superior mechanical properties and detection response to ciprofloxacin (CIP), achieved through the in-situ growth of europium-based metal-organic frameworks on TEMPO-oxidized cellulose nanofibrils (TOCNF). Firstly, Eu(III) and 2,6-pyridinedicarboxylic acid (DPA) served as precursors, and a simple self-assembly strategy was employed to grow the composite film material (Eu-DPA@TOCNF) in situ on TOCNF, which exhibited characteristic emission peaks.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!