Objective: The objective of this study was to evaluate the influence of the photoactivation source on the polymerization depth of restorative materials and its effects on resistance to enamel demineralization.
Background Data: Argon-ion laser (AL) irradiation itself provides a reduced depth of caries lesions in sound enamel.
Methods: Eighteen human teeth were sectioned into 36 blocks and distributed into two groups according to the respective restorative material: resin-modified glass ionomer material (RMGI) (Vitremer-3M ESPE; A3; n=18) and composite resin (CR) (Z350-3M ESPE; n=18). Each group was subdivided into three subgroups and activated by a quartz-tungsten-halogen (QTH) lamp, an AL, or a light-emitting diode (LED) (n=6). Knoop microhardness (KHN) analysis of the materials was evaluated at two different depths: 0 and 1.6 mm from the enamel surface. The blocks were thermocycled and submitted to five demineralization-remineralization cycles at 37°C. The KHN values of the enamel surface (0 mm) were evaluated. The specimens were longitudinally sectioned, and the restorative material was evaluated at a depth of 1.6 mm. Data were evaluated by two way analysis of variance (ANOVA) and Tukey tests (p<0.05). The evaluation of subsuperficial enamel demineralization by KHN analysis was conducted by seven indentations located at 100 μm from the restored cavity. Data were evaluated by three way ANOVA and Tukey tests (p<0.05).
Results: Comparing the two restorative materials, the KHN values at the surface (0 mm) were greater for CR, whereas at 1.6 mm, they were greater for RMGI. In addition, there was less development of enamel demineralization around RMGI restorations than CR restorations. Moreover, there were statistically significant differences on subsuperficial enamel demineralization between the two restorative materials and between the three photoactivation methods (p<0.05); RMGI presented the highest KHN values, and QTH and AL presented the lowest.
Conclusions: The photoactivation source did not influence superficial enamel demineralization, but LED activation positively influenced the subsuperficial microhardness of enamel.
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http://dx.doi.org/10.1089/pho.2013.3677 | DOI Listing |
Comput Struct Biotechnol J
December 2024
Department of Physics, University of Exeter, Stocker Rd., Exeter EX4 4QL, UK.
Magnetoreception, the ability to sense magnetic fields, is widespread in animals but remains poorly understood. The leading model links this ability in migratory birds to the photo-activation of the protein cryptochrome. Magnetic information is thought to induce structural changes in cryptochrome via a transient radical pair intermediate.
View Article and Find Full Text PDFTalanta
January 2025
College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, China. Electronic address:
Dissolved gas analysis (DGA) is an effective method for diagnosing potential faults in oil-immersed power transformers. Metal oxide semiconductor (MOS) gas sensors exhibit excellent performance. However, high operating temperatures can accelerate device aging, thereby reducing the reliability of online monitoring.
View Article and Find Full Text PDFJ Photochem Photobiol B
January 2025
Department of Chemistry, Susquehanna University, 514 University Avenue, Selinsgrove, PA 17870, USA. Electronic address:
Photopolymerization of bovine serum albumin was carried out using reactive oxygen species (ROS) generated by the irradiation of citrate-stabilized gold nanoparticles by a pulsed Nd:YAG laser. The ROS in this case, singlet oxygen (O), targets aromatic amino acids within the protein to induce photopolymerization or crosslinking. Other ROS, like the hydroxyl radical, can also form in solution and under high-energy irradiation.
View Article and Find Full Text PDFEnviron Res
December 2024
Department of Environmental Engineering, Kyungpook National University, 80 Daehak-ro, Buk-gu, Daegu, 41566, Republic of Korea. Electronic address:
Peroxydisulfate (PDS) activation is a crucial process for wastewater treatment in complicated water matrices. However, it is frequently limited because of poor selectivity, sluggish kinetics, and short lifetime of radicals. Therefore, in this study, an efficient sulfur-doped CN/DyFeO (SCN/DyF) Z-scheme heterostructure catalyst was rationally developed using a simple wet-chemical strategy to photoactivate PDS, which can effectively degrade norfloxacin (NOR; 96.
View Article and Find Full Text PDFCurr Opin Chem Biol
December 2024
Department of Chemistry and Biochemistry, The Ohio State University, Columbus, OH 43210, USA; Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095, USA. Electronic address:
Enzymes catalyze molecular reactions with remarkable efficiency and selectivity under mild conditions. Photoactivated enzymes make use of a light-absorbing chromophore to drive chemical transformations, ideally using sunlight as an energy source. The direct attachment of a chromophore to native enzymes is advantageous, as information on the underlying catalytic mechanisms can be obtained.
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