Gold and silver-gold alloy nanoparticles with mean diameter of 10nm and narrow size distribution were prepared by reduction of the correspondent metal precursors using aqueous dextran solution which acts as both a reducing and capping agent. The formation of nanoparticles was characterized by UV-vis spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD) and dynamic light scattering (DLS). The silver and gold nanoparticles exhibited absorption maxima at 425 and 551 nm respectively; while for the bimetallic Ag-Au alloy appeared 520 nm in between them. TEM images showed monodispersed particles in the range of 8-10nm. The crystallinity of the nanoparticles was assured by XRD analysis. DLS data gave particle size distribution. The dextran stabilized Au nanoparticles used as a colorimetric sensor for detection and estimation of pesticide present in water. The dextran stabilized Ag-Au alloy nanoparticles exhibited interesting antimicrobial activity against bacteria at micromolar concentrations.
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http://dx.doi.org/10.1016/j.carbpol.2014.02.047 | DOI Listing |
JACS Au
December 2024
SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States.
Establishing energy correlations among different metals can accelerate the discovery of efficient and cost-effective catalysts for complex reactions. Using a recently introduced coordination-based model, we can predict site-specific metal binding energies (Δ ) that can be used as a descriptor for chemical reactions. In this study, we have examined a range of metals including Ag, Au, Co, Cu, Ir, Ni, Os, Pd, Pt, Rh, and Ru and found linear correlations between predicted Δ and adsorption energies of CH and O (Δ and Δ ) at various coordination environments for all the considered metals.
View Article and Find Full Text PDFJ Chem Phys
December 2024
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Rotational excitations of reactants are often considered to have little impact on chemical reactivity compared to the excitations of vibrational modes and translational motion. Here, we reveal a significant influence of the rotational excitation of HCl on its dissociation on an Ag/Au(111) alloy surface. This finding is based on six-dimensional time-dependent wave packet calculations performed on an accurately fitted machine learning potential energy surface.
View Article and Find Full Text PDFAnal Chem
November 2024
Guangxi Key Laboratory of Green Processing of Sugar Resources, Department of Medicine, College of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou 545006, Guangxi, P. R. China.
In this study, we developed ratiometric surface-enhanced Raman scattering (SERS) biosensors using Ag-Au alloy nanoflowers as SERS substrates, molecules having amide bonds and alkyne groups (Tag A) as Raman reporters, and sodium thiocyanate as an internal standard molecule (Tag B) for the sensitive detection of human carboxylesterase-1 (hCE1) in HepG-2 cells. The correlation between HepG-2 cell damage and hCE1 activity levels was investigated. Both Tag A's alkyne group and Tag B's cyanide group produced characteristic SERS signals in the Raman-silent region ( and , respectively).
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
Department of Materials Science and Engineering, University of California - Davis, Davis, California 95616, United States.
Metal alloy nanostructures represent a promising platform for next-generation nanophotonic devices, surpassing the limitations of pure metals by offering additional "buttons" for tailoring their optical properties by compositional variations. While alloyed nanoparticles hold great potential, their scalability and underexplored optical behavior still limit their application. Here, we establish a systematic approach to quantifying the unique optical behavior of the AgAuPd ternary system while providing a direct comparison with its pure constituent metals.
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