Stacks and clips: Uncanny similarities in the modes of self-assembly in tenary Ag(I) complexes with 1,2-diazines and chelating heteroarenes.

CrystEngComm

Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, United States. Tel: +1 773 7022194.

Published: June 2013

The first synthesis and structural elucidation of Ag(I) ternary complexes with 1,2-diazines and chelating heteroarenes have been described. Conserved modes of inter-cation Ag⋯ and ⋯ stacking interactions result in near identical patterns of cation self-assembly in these ternary complexes.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3970789PMC
http://dx.doi.org/10.1039/C3CE40500ADOI Listing

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