We present experimental results for the angular scattering of ~1-50 keV H, He, C, O, N, Ne, and Ar ions transiting through graphene foils and compare them with scattering through nominal ~0.5 μg cm(-2) carbon foils. Thin carbon foils play a critical role in time-of-flight ion mass spectrometers and energetic neutral atom sensors in space. These instruments take advantage of the charge exchange and secondary electron emission produced as ions or neutral atoms transit these foils. This interaction also produces angular scattering and energy straggling for the incident ion or neutral atom that acts to decrease the performance of a given instrument. Our results show that the angular scattering of ions through graphene is less pronounced than through the state-of-the-art 0.5 μg cm(-2) carbon foils used in space-based particle detectors. At energies less than 50 keV, the scattering angle half width at half maximum, ψ(1/2), for ~3-5 atoms thick graphene is up to a factor of 3.5 smaller than for 0.5 μg cm(-2) (~20 atoms thick) carbon foils. Thus, graphene foils have the potential to improve the performance of space-based plasma instruments for energies below ~50 keV.
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http://dx.doi.org/10.1063/1.4866850 | DOI Listing |
Waste Manag
December 2024
National Engineering Research Center of Green Recycling for Strategic Metal Resources, Chemistry & Chemical Engineering Data Center, Chinese Academy of Sciences, Institute of Process Engineering, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100190, China. Electronic address:
Recycling of spent lithium-ion batteries has attracted worldwide attention to ensure sustainability of electric vehicle industry. Pretreatment as an essential step for recycling of spent LIBs is critical to ensure the recovery efficiency and quality of black mass which is used for further materials regeneration. Usually, high temperature pyrolysis, at around 600 °C is required during the pretreatment to achieve effective separation of the black mass that is binding on aluminium foils with polyvinylidene fluoride binder.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
December 2024
Center for Transport Technologies, Battery Technologies, AIT Austrian Institute of Technology GmbH, Giefinggasse 2, Vienna 1210, Austria.
In this work, a battery layup consisting of a poorly flammable ionic liquid electrolyte and a poly(vinylidene fluoride--hexafluoropropylene) (PVdF-HFP) thermoplastic has been developed along with composite anode and cathode electrodes. The developed gel electrolyte exhibits feasible ionic conductivity of about 1 mS/cm at 30 °C. State-of-the-art active electrode materials, i.
View Article and Find Full Text PDFTalanta
March 2025
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing, 210023, PR China. Electronic address:
The pH of environmental systems plays a crucial role in determining pollutant behavior, necessitating the development of effective tools for real-time monitoring. This study introduces a novel series of lipophilic HPTS derivatives, developed through a two-step synthesis route, designed as pH-sensitive dyes, characterized by high fluorescence intensity, photostability, dual excitation/single emission, and significant Stokes shifts. We engineered self-ratiometric pH-sensing planar optode foils and investigated the impact of carbon chain length on foil durability.
View Article and Find Full Text PDFACS Catal
November 2024
Institute of Materials Chemistry, TU Wien, Getreidemarkt 9/BC, 1060 Vienna, Austria.
A combined surface science/microreactor approach was applied to examine interface effects in ethylene hydrogenation on carbon-supported Ag, Au, and Cu nanoparticle catalysts. Turnover frequencies (TOFs) were substantially higher for supported catalysts than for (unsupported) polycrystalline metal foils, especially for Ag. Spark ablation of the corresponding metals on highly oriented pyrolytic graphite (HOPG) and carbon-coated grids yielded nanoparticles of around 3 nm size that were well-suited for characterization by X-ray photoelectron spectroscopy (XPS), high-resolution (scanning) transmission electron microscopy (HRTEM/STEM), and energy dispersive X-ray spectroscopy (EDX).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Center for Multidimensional Carbon Materials (CMCM), Institute for Basic Science (IBS), 44919, Ulsan, Republic of Korea.
Chemical vapor deposition of carbon precursors on Cu-based substrates at temperatures exceeding 1000 °C is currently a typical route for the scalable synthesis of large-area high-quality single-layer graphene (SLG) films. Using molecules with higher activities than CH may afford lower growth temperatures that might yield fold- and wrinkle-free graphene. The kinetics of growth of graphene using hydrocarbons other than CH are of interest to the scientific and industrial communities.
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