A mild synthesis of new aryl vinyl ethers and diethyl 1-[(alkyl)(cyano)methyl]vinylphosphonates via the substitution of a 2,3-difunctional allyl bromide.

Asma Fray Jihène Ben Kraïem Aïcha Arfaoui Hassen Amri

ScientificWorldJournal

Selective Organic Synthesis & Biological Activity, Faculty of Science, El Manar University, 2092 Tunis, Tunisia.

Published: December 2014

A novel class of aryl vinyl ethers 3 and diethyl 3-cyano-3-alkylprop-1-en-2-ylphosphonates 4 has been prepared, respectively, from coupling reaction of diethyl 1-(bromomethyl)-2-cyanovinylphosphonate 2 with phenols and Gilman reagents.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3943250	PMC
http://dx.doi.org/10.1155/2014/260325	DOI Listing

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