We report on the dynamics of ultrafast heating in cryogenic hydrogen initiated by a ≲300 fs, 92 eV free electron laser x-ray burst. The rise of the x-ray scattering amplitude from a second x-ray pulse probes the transition from dense cryogenic molecular hydrogen to a nearly uncorrelated plasmalike structure, indicating an electron-ion equilibration time of ∼0.9 ps. The rise time agrees with radiation hydrodynamics simulations based on a conductivity model for partially ionized plasma that is validated by two-temperature density-functional theory.
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http://dx.doi.org/10.1103/PhysRevLett.112.105002 | DOI Listing |
Nano Lett
December 2024
Department of Electrical Engineering, Ginzton Laboratory, Stanford University, Stanford, California 94305, United States.
Heterostructures composed of graphene and molybdenum trioxide (MoO) can support in-plane hybrid polaritons in the infrared. The isofrequency contour for these subwavelength polaritons can exhibit a quasi-flat region when the topological transition occurs as the doping level of graphene is tuned. Such a topological transition can be useful for optical sensing and imaging at nanoscale.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Nanomaterials Physicochemistry, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Piastów 42, 71-065 Szczecin, Poland.
Herein, we propose a general route of obtaining reduced graphene oxide and metal oxide nanocomposite, demonstrated by cerium, dysprosium, and neodymium sesquioxides, via ultrafast redox reaction (URR). This method utilizes a very fast heating of graphene oxide and a metal salt without any chemical solvents or special reactors. Off the scene tests showed that different ratios of graphene oxide to metal salt change the metal oxide particle size.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Institut National de la Recherche Scientifique (INRS), Centre Énergie Matériaux Télécommunications, Varennes, Québec, J3X 1P7, Canada.
The production of storable hydrogen fuel through water electrolysis powered by renewable energy sources such as solar, marine, geothermal, and wind energy presents a promising pathway toward achieving energy sustainability. Nevertheless, state-of-the-art electrolysis requires support from ancillary processes which often incur financial and energy costs. Developing electrolysers capable of directly operating with water that contains impurities can circumvent these processes.
View Article and Find Full Text PDFLangmuir
December 2024
National Energy Coal Gasification Technology Research and Development Center, East China University of Science and Technology, P.O. Box 272, Shanghai 200237, P. R. China.
Carbon black from methane pyrolysis for hydrogen is an alternative resource and can be improved for conductive material supplication. Our current work uses an ultrafast Joule heating technique to modify the methane-pyrolyzed carbon black and prepare nanoparticles of electrode material for supercapacitor application, coupled with density functional theory, structural, and electrochemical analyses. Evolution rules of the carbon and pore structures of the modified sample with an increase in temperature reveal good structure improvements.
View Article and Find Full Text PDFMicron
December 2024
Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea; Institute for Convergence Research and Education in Advanced Technology, Yonsei University, Seoul 03722, Republic of Korea; Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan.
Electron-beam irradiation of α-Mn triggers dramatic microstructural transformations. Transmission electron microscopy (TEM) reveals localized thinning and MnO formation within the irradiated area. Reduced thermal conductivity due to thinning suggests significant local temperature rise by electron-beam irradiation.
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