Switchable, double wavelength generation is demonstrated from a single vertical external cavity surface-emitting laser chip. Power of ~0.5 W for two wavelengths λ≈967 nm and 1,018 nm i.e. within the spectral distance of 51 nm were registered. In the semiconductor heterostructure a single set of nominally identical quantum wells was enclosed in a single, two-mode resonant microcavity. The wavelength switching was induced by the change of the pump power. The increase or decrease of the pump power changes the active region temperature and thus tunes spectrally the gain spectrum to the one of two modes.
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http://dx.doi.org/10.1364/OE.22.006447 | DOI Listing |
Chem Sci
December 2024
Center for Bioanalytical Chemistry, University of Science and Technology of China Hefei 230026 China
Molecule-electrode interactions are critical for determining transport mechanisms and device functionalities in both single-molecule electrochemistry and electronics. Crucial factors such as anchoring groups and local fields have been studied, but the role of electrolytes and interfacial charge distribution remains largely underexplored. The present research focuses on how the interfacial charge distribution in the electric double layer (EDL) controls single-molecule junctions anchored by azulene.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Faculty of Pharmaceutical Sciences, Hokkaido University, Kita-ku, Sapporo, Japan.
A site-selective functionalization of a C(sp)-H bond was achieved in the presence of an intrinsically more reactive C(sp)-H bond by controlling the orientation of a directing group via a photo-induced E/Z isomerization of an oxime ether. By combining E/Z isomerization and an electron deficient Cp*Ir(III) catalyst, the scope of oxime ethers in C(sp)-H functionalization was successfully expanded. Based on this strategy, the order of C-H activation was switchable and successive C(sp)-H/C(sp)-H and C(sp)-H/C(sp)-H double functionalizations were accomplished to construct densely functionalized structures.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
School of Physical Science and Technology, Shanghai Key Laboratory of High-Resolution Electron Microscopy, State Key Laboratory of Advanced Medical Materials and Devices, ShanghaiTech University, Shanghai 201210, China.
Absorptive frequency-selective transmission/reflection (AFST/AFSR) metamaterials (MMs) embedded with yttrium-iron-garnet are proposed, capable of achieving angular-insensitive and switchable octave absorption. The season optimization algorithm is utilized to optimize the structural parameters of the MM, thus achieving exceptional angular stability. By adjusting the discrete decreasing magnetic field applied to the MM, it can freely switch between double, triple, quadruple, and fivefold octave absorptions.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2025
Laboratoire Softmat, University of Toulouse, CNRS UMR 5623, University Toulouse III - Paul Sabatier, 118, route de Narbonne 31062 Toulouse Cedex 9, France. Electronic address:
The growing demand of novel hybrid organic/inorganic systems with exciting properties has contributed to an increasing need for simplifying production strategies. Here, we report a simple method to obtain controlled three-dimensional hybrid architectures, in particular hybrid supracolloids (hSC), formed by gold nanoparticles and a double hydrophilic block copolymer, specifically the poly(acrylic acid)-block-poly(N-vinyl-2-pyrrolidone) (PAA-b-PVP), directly in aqueous medium. The ubiquitous pH-sensitive poly(acrylic acid) (PAA) block initiates the assembly through pH changes, while the poly(N-vinyl-2-pyrrolidone) block assures the close affinity with the AuNPs.
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