We present numerical simulations that allow us to compute the number of ways in which N particles can pack into a given volume V. Our technique modifies the method of Xu, Frenkel, and Liu [Phys. Rev. Lett. 106, 245502 (2011)] and outperforms existing direct enumeration methods by more than 200 orders of magnitude. We use our approach to study the system size dependence of the number of distinct packings of a system of up to 128 polydisperse soft disks. We show that, even though granular particles are distinguishable, we have to include a factor 1=N! to ensure that the entropy does not change when exchanging particles between systems in the same macroscopic state. Our simulations provide strong evidence that the packing entropy, when properly defined, is extensive. As different packings are created with unequal probabilities, it is natural to express the packing entropy as S = − Σ(i)p(i) ln pi − lnN!, where pi denotes the probability to generate the ith packing. We can compute this quantity reliably and it is also extensive. The granular entropy thus (re)defined, while distinct from the one proposed by Edwards [J. Phys. Condens. Matter 2, SA63 (1990)], does have all the properties Edwards assumed.
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http://dx.doi.org/10.1103/PhysRevLett.112.098002 | DOI Listing |
Water Res
September 2024
Department of Technology, Management and Economics, Technical University of Denmark, 2800, Kgs. Lyngby, Denmark. Electronic address:
PLoS One
June 2024
Department of Biostatistics, Data Science and Epidemiology, Georgia Cancer Center at Augusta University, Augusta, GA, United States of America.
Clustering is an important task in biomedical science, and it is widely believed that different data sets are best clustered using different algorithms. When choosing between clustering algorithms on the same data set, reseachers typically rely on global measures of quality, such as the mean silhouette width, and overlook the fine details of clustering. However, the silhouette width actually computes scores that describe how well each individual element is clustered.
View Article and Find Full Text PDFUltrason Sonochem
June 2024
Department of Mechanical Engineering, Faculty of Engineering, Fasa University, Fasa, Iran.
Present study investigates the effects of probe size geometry on thermodynamic kinetics, rheology, and microstructure of wheat and tapioca starch. Ultrasound treatment using different probe diameters (20 mm and 100 mm) significantly influenced the gelatinization process. Results showed reduced enthalpy (ΔH) and Gibbs energy (ΔG), indicating enhanced gelatinization efficiency.
View Article and Find Full Text PDFEntropy (Basel)
March 2024
Departamento de Física and Instituto de Computación Científica Avanzada (ICCAEx), Universidad de Extremadura, Avda. de Elvas s/n, E-06006 Badajoz, Spain.
The Boltzmann kinetic equation for dilute granular suspensions under simple (or uniform) shear flow (USF) is considered to determine the non-Newtonian transport properties of the system. In contrast to previous attempts based on a coarse-grained description, our suspension model accounts for the real collisions between grains and particles of the surrounding molecular gas. The latter is modeled as a bath (or thermostat) of elastic hard spheres at a given temperature.
View Article and Find Full Text PDFEntropy (Basel)
March 2024
The Works Research Institute, H-1044 Budapest, Hungary.
In general, sound waves propagate radially outwards from a point source. These waves will continue in the same direction, decreasing in intensity, unless a boundary condition is met. To arrive at a universal understanding of the relation between frequency and wave propagation within spatial boundaries, we explore the maximum entropy states that are realized as resonant modes.
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