Recent discoveries of water-rich lunar apatite are more consistent with the hydrous magmas of Earth than the otherwise volatile-depleted rocks of the Moon. Paradoxically, this requires H-rich minerals to form in rocks that are otherwise nearly anhydrous. We modeled existing data from the literature, finding that nominally anhydrous minerals do not sufficiently fractionate H from F and Cl to generate H-rich apatite. Hydrous apatites are explained as the products of apatite-induced low magmatic fluorine, which increases the H/F ratio in melt and apatite. Mare basalts may contain hydrogen-rich apatite, but lunar magmas were most likely poor in hydrogen, in agreement with the volatile depletion that is both observed in lunar rocks and required for canonical giant-impact models of the formation of the Moon.
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http://dx.doi.org/10.1126/science.1250398 | DOI Listing |
Commun Earth Environ
November 2023
Materials Science and Technology Division, U.S. Naval Research Laboratory, Washington, DC 20375 USA.
Water on the surface of the Moon is a potentially vital resource for future lunar bases and longer-range space exploration. Effective use of the resource depends on developing an understanding of where and how within the regolith the water is formed and retained. Solar wind hydrogen, which can form molecular hydrogen, water and/or hydroxyl on the lunar surface, reacts and is retained differently depending on regolith mineral content, thermal history, and other variables.
View Article and Find Full Text PDFNat Commun
June 2022
Key Laboratory of Lunar and Deep Space Exploration, National Astronomical Observatories, Chinese Academy of Sciences, Beijing, 100101, China.
The distribution range, time-varying characteristics, and sources of lunar water are still controversial. Here we show the Chang'E-5 in-situ spectral observations of lunar water under Earth's magnetosphere shielding and relatively high temperatures. Our results show the hydroxyl contents of lunar soils in Chang'E-5 landing site are with a mean value of 28.
View Article and Find Full Text PDFNature
December 2021
Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China.
The distribution of water in the Moon's interior carries implications for the origin of the Moon, the crystallization of the lunar magma ocean and the duration of lunar volcanism. The Chang'e-5 mission returned some of the youngest mare basalt samples reported so far, dated at 2.0 billion years ago (Ga), from the northwestern Procellarum KREEP Terrane, providing a probe into the spatiotemporal evolution of lunar water.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
September 2020
Jacob-Johnson Space Center Engineering, Technology and Science Contract, The Lyndon B. Johnson Space Center, National Aeronautics and Space Administration, Houston, TX 77058.
Lunar mare basalts are depleted in F and Cl by approximately an order of magnitude relative to mid-ocean ridge basalts and contain two Cl-bearing components with elevated isotopic compositions relative to the bulk-Earth value of ∼0‰. The first is a water-soluble chloride constituting 65 ± 10% of total Cl with δCl values averaging 3.0 ± 4.
View Article and Find Full Text PDFNatl Sci Rev
November 2019
Department of Earth Sciences, Vrije Universiteit Amsterdam, Amsterdam 1081 HV, The Netherlands.
The traditional view of a dry, volatile-poor Moon has been challenged by the identification of water and other volatiles in lunar samples, but the volatile budget delivery time(s), source(s) and temporal evolution remain poorly constrained. Here we show that hydrogen and chlorine isotopic ratios in lunar apatite changed significantly during the Late Accretion (LA, 4.1-3.
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