Construction of high-energy-density supercapacitors from pine-cone-derived high-surface-area carbons.

ChemSusChem

Faculty of Applied Chemical Engineering, Chonnam National University, Gwang-ju 500-757 (Republic of Korea); Department of Mechanical and Materials Engineering, The University of Western Ontario, London, Ontario, N6 A 5B9 (Canada).

Published: May 2014

Very high surface area activated carbons (AC) are synthesized from pine cone petals by a chemical activation process and subsequently evaluated as an electrode material for supercapacitor applications in a nonaqueous medium. The maximum specific surface area of ∼3950 m(2)  g(-1) is noted for the material treated with a 1:5 ratio of KOH to pine cone petals (PCC5), which is much higher than that reported for carbonaceous materials derived from various other biomass precursors. A symmetric supercapacitor is fabricated with PCC5 electrodes, and the results showed enhanced supercapacitive behavior with the highest energy density of ∼61 Wh kg(-1). Furthermore, outstanding cycling ability is evidenced for such a configuration, and ∼90 % of the initial specific capacitance after 20,000 cycles under harsh conditions was observed. This result revealed that the pine-cone-derived high-surface-area AC can be used effectively as a promising electrode material to construct high-energy-density supercapacitors.

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http://dx.doi.org/10.1002/cssc.201301262DOI Listing

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