Hierarchical coarsening in the late stage of viscoelastic phase separation.

Soft Matter

Beijing National Laboratory for Molecular Sciences, Joint Laboratory of Polymer Science and Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Published: April 2014

Coarsening is a general phenomenon in phase separating mixtures. In this study, we report a hierarchical coarsening at different length scales. Dispersed domains grew by direct combination of two/three small ones while some small domains can survive for a long time. The small angle laser light scattering showed that the scattered intensity exhibited multiple "decay-growth" transitions in the coarsening process. The evolution of the main peak gave a characteristic power law index of about -3/4, which is much faster than the -1/3 relationship from the traditional theories. We propose that relaxation and hydrodynamic flow play important roles in this process.

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http://dx.doi.org/10.1039/c3sm52713aDOI Listing

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