Coarsening is a general phenomenon in phase separating mixtures. In this study, we report a hierarchical coarsening at different length scales. Dispersed domains grew by direct combination of two/three small ones while some small domains can survive for a long time. The small angle laser light scattering showed that the scattered intensity exhibited multiple "decay-growth" transitions in the coarsening process. The evolution of the main peak gave a characteristic power law index of about -3/4, which is much faster than the -1/3 relationship from the traditional theories. We propose that relaxation and hydrodynamic flow play important roles in this process.
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http://dx.doi.org/10.1039/c3sm52713a | DOI Listing |
J Chem Inf Model
January 2025
Department of Chemical Engineering, Department of Computer Science, University of California Berkeley, Berkeley, California 94720, United States.
Molecular conformer generation (MCG) is an important task in cheminformatics and drug discovery. The ability to efficiently generate low-energy 3D structures can avoid expensive quantum mechanical simulations, leading to accelerated virtual screenings and enhanced structural exploration. Several generative models have been developed for MCG, but many struggle to consistently produce high-quality conformers for meaningful downstream applications.
View Article and Find Full Text PDFPhys Chem Chem Phys
April 2024
Nanoelectronics Laboratory, Graduate School of Information Science and Technology, Hokkaido University, Sapporo, 060-0814, Japan.
We investigated the hierarchical structure growth of myristic acid monolayers at the air-water interface across different length scales in the two-phase coexistence region of the first order liquid expanded (LE)-liquid condensed (LC) phase transition. A combined study of surface pressure-area (π-) isotherm measurements with Brewster angle microscopy (BAM) observations was done at different temperatures. At the nanometer scale, the analysis of the π- isotherm by application of a thermodynamic cluster equation allowed us to obtain the π dependence of cluster size (cluster distribution) in the LE-LC coexistence region.
View Article and Find Full Text PDFMaterials (Basel)
February 2024
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China.
This study investigates the influence of varying austenitizing temperatures on the microstructure and mechanical properties of 35Si2MnCr2Ni3MoV steel, utilizing Charpy impact testing and microscopic analysis techniques such as scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). The findings reveal that optimal combination of strength and toughness is achieved at an austenitizing temperature of 980 °C, resulting in an impact toughness of 67.2 J and a tensile strength of 2032 MPa.
View Article and Find Full Text PDFACS Nano
February 2024
Department of Chemistry, University of California, Berkeley, California 94720, United States.
Self-assembly of colloidal nanocrystals (NCs) into superlattices (SLs) is an appealing strategy to design hierarchically organized materials with promising functionalities. Mechanistic studies are still needed to uncover the design principles for SL self-assembly, but such studies have been difficult to perform due to the fast time and short length scales of NC systems. To address this challenge, we developed an apparatus to directly measure the evolving phases and in real time of an electrostatically stabilized Au NC solution before, during, and after it is quenched to form SLs using small-angle X-ray scattering.
View Article and Find Full Text PDFChem Commun (Camb)
October 2023
Shanghai Engineering Research Center of Hierarchical Nanomaterials, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science & Technology, Shanghai 200237, China.
An o-PtFe/C intermetallic catalyst was prepared by a facile thermal reduction method with the average particle size of only 6.6 nm in the presence of urea. The loss of mass activity is only 25.
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