AI Article Synopsis
- A 3D Cu(I)-polymeric complex, Cu2L(NO3)2(DMF)0.4, can visibly change into a 1D Cu(II) polymeric complex when placed in methanol (CH3OH) and exposed to air.
- The newly formed complex is identified as Cu(μ-OCH3)(L)(NO3).
- The study also looks into the process that drives this transformation from the 3D to the 1D structure.
Article Abstract
An interesting irreversible structural transformation visible to the naked-eye occurs when a 3D Cu(I)-polymeric complex Cu2L(NO3)2(DMF)0.4 (1) is suspended in CH3OH in air to produce a 1D-Cu(II) polymeric complex Cu(μ-OCH3)(L)(NO3) (2) (L = 1,2-bis[4-(pyrimidin-4-yl)phenoxy]ethane). The transformation mechanism from 1 to 2 was also investigated.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c4cc00857j | DOI Listing |
Publication Analysis
Top Keywords
structural transformation
8
oxygen methanol
4
methanol mediated
4
mediated irreversible
4
irreversible coordination
4
coordination polymer
4
polymer structural
4
transformation cui-framework
4
cui-framework cuii-chain
4
cuii-chain interesting
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!