The aim of this work is to present a method based on asymmetric flow-field-flow-fractionation coupled on-line to a static light scattering (AF4-UV-SLS) detector to characterize self-assembled nanofibers (NFs). The method developed herein allows the determination of both the length distribution of the NFs as well as the distribution in terms of aggregation number per unit length (Agg). Given the remaining synthetic challenges of better controlling the structural homogeneity and particle dimensions, the NF length and aggregation number per unit length are becoming essential for the improvement and control of their chemical processes and a better understanding of their properties. The results obtained with this AF4-UV-SLS method indicate that a well-resolved NF length distribution characterization and Agg determination were attained. These results provide critical information concerning the physical properties of the investigated NFs and open the door to the characterization of new self-assembled polymers with various asymmetrical architectures.
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http://dx.doi.org/10.1016/j.aca.2014.02.011 | DOI Listing |
J Clin Med
December 2024
Department of Orthopaedic Surgery, Institute of Medicine, University of Tsukuba, 1-1-1, Tennodai, Tsukuba 305-8575, Ibaraki, Japan.
Proximal femoral fractures are particularly common in older adults, and cases requiring conversion to total hip arthroplasty may arise because of treatment failure or osteoarthritis. Fractures around the distal screw removal holes can be problematic. This study aimed to analyze the relationship between stem length and femoral stress distribution to determine the optimal stem length.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Tickle College of Engineering, University of Tennessee, Knoxville, TN 37996, USA.
Pultruded carbon fiber-reinforced composites are attractive to the wind energy industry due to the rapid production of highly aligned unidirectional composites with enhanced fiber volume fractions and increased specific strength and stiffness. However, high volume carbon fiber manufacturing remains cost-prohibitive. This study investigates the feasibility of a pultruded low-cost textile carbon fiber-reinforced epoxy composite as a promising material in spar cap production was undertaken based on mechanical response to four-point flexure loading.
View Article and Find Full Text PDFPlants (Basel)
December 2024
Co-Innovation Center for Sustainable Forestry in Southern China, Bamboo Research Institute, Nanjing Forestry University, #159 Longpan Road, Nanjing 210037, China.
Total leaf area per shoot () can reflect the photosynthetic capacity of a shoot. A prior study hypothesized that is proportional to the product of the sum of the individual leaf widths per shoot () and the maximum individual leaf length per shoot (), referred to as the Montgomery-Koyama-Smith equation (MKSE). However, empirical evidence does not support such a proportional relationship hypothesis, as was found to allometrically scale with , i.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Crop Science, Kyungpook National University, Sangju, 37224, Kyungpook, South Korea.
The genus Vandenboschia exhibits significant diversity, driven by complex hybridization events and varying ploidy levels in the natural habitats of Korea, leads to misidentifications that obscure its true distribution and classification. To address this issue, the present study employed morphological, cytological, and genotype analyses to clarify the taxonomical circumscription and distribution patterns of the Vandenboschia radicans complex in Korea. The V.
View Article and Find Full Text PDFMedicine (Baltimore)
January 2025
Teaching Office, Second People's Hospital of Shenzhen (First Affiliated Hospital of Shenzhen University), Shenzhen City, China.
Previous studies have provided relatively limited evidence in examining the impact of preoperative serum albumin levels on the length of hospital stay (LOS) in patients with hip fractures. This study aimed to elucidate the association between preoperative serum albumin levels and LOS in elderly patients with hip fractures. This retrospective cohort study included 1444 elderly patients undergoing surgical treatment for hip fractures at the Second People's Hospital of Shenzhen from January 2012 to December 2021.
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