This paper describes the fabrication of scanning probes with single metal nanowires (NWs) at the probe tip. The porous-template technique can produce NWs of various kinds of metals, with diameters down to 10-20 nm, which compete with multiwall carbon nanotube diameters. Metal NWs are grown by electrodeposition on the scanning probe tip. One NW can be selected to remain by focused ion beam technique. A variety of metals can be chosen as the tip material. Electric potentials of NWs at the probe tip can be measured. Single NW probes can measure surface topographies, electrode potentials, and their mechanical bending properties.
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http://dx.doi.org/10.1021/nn4066582 | DOI Listing |
ACS Biomater Sci Eng
January 2025
Xiangya School of Stomatology, Central South University, Changsha 410008, Hunan, China.
In the context of regenerative medicine, the design of scaffolds to possess excellent osteogenesis and appropriate mechanical properties has gained significant attention in bone tissue engineering. In this review, we categorized materials into metallic, inorganic, nonmetallic, organic polymer, and composite materials. This review provides a more integrated and multidimensional analysis of scaffold design for bone tissue engineering.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics and Engineering Physics, Tulane University, New Orleans, Louisiana 70118, United States.
Herein, we report the synthesis of two-dimensional TaSeC (2D-TaSeC) nanosheets using electrochemical lithiation in multilayer TaSeC followed by sonication in deionized water. Multilayer TaSeC was obtained via solid-state synthesis of FeTaSeC followed by chemical etching of Fe. 2D-TaSeC exhibited promising electrocatalytic activity for the hydrogen evolution reaction from water compared to multilayer TaSeC and 2D-TaSe.
View Article and Find Full Text PDFSmall
January 2025
Chongqing Key Laboratory of Prevention and Treatment for Occupational Diseases and Poisoning, First Affiliated Hospital of Chongqing Medical and Pharmaceutical College, Chongqing, 400060, China.
Nanozyme-based colorimetric sensors are promising approaches for environmental monitoring, food safety, and medical diagnostics. However, developing novel nanozymes that exhibit high catalytic activity, good dispersion in aqueous solution, high sensitivity, selectivity, and stability is challenging. In this study, for the first time, single-atom iridium-doped carbon dot nanozymes (SA Ir-CDs) are synthesized via a simple in situ pyrolysis process.
View Article and Find Full Text PDFAdv Mater
January 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, China.
The design and synthesis of metal-organic frameworks (MOFs) with outstanding light-harvesting and photoexcitation for artificial photocatalytic CO reduction is an attractive but challenging task. In this work, a novel aggregation-induced emission (AIE)-active ligand, tetraphenylpyrazine (PTTBPC) is proposed and utilized for the first time to construct a Zr-MOF photocatalyst via coordination with stable Zr-oxo clusters. Zr-MOF is featured by a scu topology with a two-fold interpenetrated framework, wherein the PTTBPC ligands enable strong light-harvesting and photoexcitation, while the Zr-oxo clusters facilitate CO adsorption and activation, as well as offer potential sites for further metal modification.
View Article and Find Full Text PDFChemistry
January 2025
Politecnico di Milano, Department of Chemistry, Materials, Chemical Engineer., via Mancinelli 7, 20131, Milan, ITALY.
Molecular recognition mediated by s-hole interactions is enhanced as the electrostatic potential at the σ-hole becomes increasingly positive. Traditional methods to strengthen σ-hole donor ability of atoms such as halogens often involve covalent modifications, such as, introducing electron-withdrawing substituents (neutral or positively charged) or electrochemical oxidation. Metal coordination, a relatively underexplored approach, offers a promising alternative.
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