Carbohydrate-based Cu(I) stabilizing ligands and their use in the synthesis of carbohydrate-ferrocene conjugates.

Carbohydr Res

MCAT GmbH, Hermann-von-Vicari-Str. 23, 78464 Konstanz, Germany. Electronic address:

Published: March 2014

A series of carbohydrate-ferrocene conjugates have been synthesized by copper(I)-catalyzed cycloaddition of carbohydrate-azides and ethynylferrocene (CuAAC). Newly carbohydrate-based tris-triazoles have been used as Cu(I) stabilizing ligands and showed at least comparable, in some cases even better results compared to the use of tris-(benzyltriazolylmethyl)amine (TBTA).

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http://dx.doi.org/10.1016/j.carres.2014.01.005DOI Listing

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